平板式直接内重整体氧化物燃料电池的一维动态建模与仿真_英文_.docxVIP

PRODUCT ENGINEERING AND CHEMICAL TECHNOLOGY Chinese Journal of Chemical Engineering, 17(2) 304—317 (2009) One-dimensional Dynamic Modeling and Simulation of a Planar Direct Internal Reforming Solid Oxide Fuel Cell* KANG Yingwei (康英伟)1,**, LI Jun (李俊)1, CAO Guangyi (曹广益)1, TU Hengyong (屠恒勇)1, LI Jian (李箭)2 and YANG Jie (杨杰)2 1 Institute of Fuel Cell, Shanghai Jiao Tong University, Shanghai 200240, China 2 School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China Abstract This article aims to investigate the transient behavior of a planar direct internal reforming solid oxide fuel cell (DIR-SOFC) comprehensively. A one-dimensional dynamic model of a planar DIR-SOFC is first devel- oped based on mass and energy balances, and electrochemical principles. Further, a solution strategy is presented to solve the model, and the International Energy Agency (IEA) benchmark test is used to validate the model. Then, through model-based simulations, the steady-state performance of a co-flow planar DIR-SOFC under specified ini- tial operating conditions and its dynamic response to introduced operating parameter disturbances are studied. The dynamic responses of important SOFC variables, such as cell temperature, current density, and cell voltage are all investigated when the SOFC is subjected to the step-changes in various operating parameters including both the load current and the inlet fuel and air flow rates. The results indicate that the rapid dynamics of the current density and the cell voltage are mainly influenced by the gas composition, particularly the H2 molar fraction in anode gas channels, while their slow dynamics are both dominated by the SOLID (including the PEN and interconnects) tem- perature. As the load current increases, the SOLID temperature and the maximum SOLID temperature gradient both increase, and thereby, the cell breakdown is apt to occur because of excessive thermal stresses. Changing the inlet fue