嵌段共聚物胶束法制备纳米阵列及其荧光增强效应研究-化学工程与技术专业论文.pdf.docxVIP

广东工业大学硕士学位论文纳米颗粒阵列上的荧光强度被大大地增强了。 广东工业大学硕士学位论文 纳米颗粒阵列上的荧光强度被大大地增强了。 本文通过两个简单的步骤制备了Au／ZnO双纳米颗粒阵列。首先，用嵌段共聚物 胶束法在硅衬底制备Au纳米颗粒阵列。然后以Zn(CH3COO)2作为前驱体，在制备好 的Au纳米颗粒阵列上制备ZnO纳米颗粒阵列，组成Au／ZnO双纳米颗粒阵列。对其 消光光谱进行分析表明，ZnO的加入并没有使Au纳米颗粒阵列的表面等离子体共振 性质发生变化。而荧光光谱分析结果显示，与Au纳米颗粒阵列相比，双组分纳米颗 粒阵列上P3HT的荧光强度更高。 关键词：嵌段共聚物；Au纳米颗粒阵列；Au／ZnO双纳米颗粒阵列；表面增强荧光； 表面等离子体共振 II 万方数据 AbslraotAbstract Abslraot Abstract Fluorescence-based devices and techniques have been widely used in the field of chemistry,biology,medicine，photonics，and materials science．Enhancing the fluorescence intensity of fluorophore would greatly improve the performance of optoelectronic devices as well as other fluorescence-based techniques．One of important strategies to achieve fluorescence enhancement is utilizing noble metal nanostructures due to the generation of surface plasmon resonances upon resonant light excitation．At present，a wide range of metal nanostructures such as nanowires，nanorods，nanoholes，nanotriangles，have been reported to elIhance fluorescence of various fluorophores，especially sinail dye molecules．However, fluorescence enhancement based on highly ordered metal nanoarray substrates was rarely reported．To fabricate highly ordered nanoarrays as metal-enhanced fluorescence(MEF) substrates，a number of methods have been developed，including anodic alumimum oxide (AAO)template deposition,electron-beam lithography，polystyrene mierospheres template deposition and SO on． Here we report a simple and economical approach for fabricating large-area and well-ordered nanoparticle arrays on silicon substrate by block copolymer micelle self-assembly．The morphologies and compositions were characterized using scanning electron microscope(SEM)，transmission electron microscopy(删，and energy dispersive spectrometer(EDS)．Moreover,fluorescence enhancement effect of poly(3一hexylthiophene)(P3HT)on different kinds of nanoparticle arrays were systematically investigated by ultraviolet and visible spectrometer，fluorescence spectrometer,Raman