硅油煤沥青乳液制备中间相炭微球-材料工程.PDFVIP

56 / 2010 3 / Preparation of Mesocarbon Microbeads w ith Silicone Oil/ Pitch Emulsion , , , , , ( , 710072) HENG Youliang, LI T iehu, LI Fengjuan, ZHUANG Qiang, JING Deqi, ZHAO T ingkai (School of Materials Science, Northwestern Polytechnical University, Xian 710072, hina) : , ,/ (Mesocarbon Microbeads, M MB) SEMXRD , M MB :M MB , , M MB ,, ,, ,( THFI) , M MB ,, THFI ,/ 31 , , D50 0.82m, , 8.2%M MB : ; ; ; / : T Q1271 : A : 2010 Abstract: Mesocarbon Microbeads (M MB) were prepared by heat condensation in the retort with coal tar pitch and silicone oil as the dispersion and heat exchange medium. T he influence of silicone oil on the preparation of M MB was studied by SEM, laser particle size analyzer and XRD. The results showed that silicone oil content had an important influence on the formation of M MB. After the ad dition of silicone oil, the spheres with uniform distribution and smooth surface had smaller diameter and better crystallite structure. At the same time, the yield of TH FI and surface adhesion between spheres decreased. With increasing silicone oil content, the diameter and crystallite structure of the spheres were hardly changed. T he spheres presented better dispersion and the yield increased, while some small particles attached to the surface of M MB. When the ration of silicon oil/ pitch was 3 1, M MB with uniform size distribution and smooth surface were obtained. D 50 of M MB was 0. 82m, and the yield of THFI was 8.2% . Key words: coal tar pitch;heat condensation; M MB; silicone oil/ pitch emulsion