臭氧氧化分解二乙基二硫代氨基甲酸钠机理研究环境科学与工程专业论文.docxVIP

广东工业大学硕士学位论文最终被氧化分解为结构简单的N，N---乙基甲酰胺(CsHnNO)。液相中除了N；N．二乙 广东工业大学硕士学位论文 最终被氧化分解为结构简单的N，N---乙基甲酰胺(CsHnNO)。液相中除了N；N．二乙 基甲酰胺，还存在着S042。、N02、N03和NH4+四种无机态离子。 最后，利用臭氧氧化法联合传统混凝技术对广西某铅锌矿浮选废水进行深度净化 试验，并探讨了相关机理。结果表明，臭氧可将废水中的可溶性有机磷转化成磷酸根 无机磷形式，然后再与传统混凝剂结合产生稳定沉淀。此法处理后水质符合《铅、锌 工业污染物排放标准》(GB25466．2010)，特别的，总磷(TP)浓度由1．4—1．7mg／L下 降至0．2一O．4 mg／L，明显低于≤1．0 mg／L的排放标准。 关键词：二乙基二硫代氨基甲酸钠；选矿废水；臭氧氧化；元素迁移；分解机理 万方数据 AB AB STRACT The organic sulfhydryl compounds is one of the most commonly used coilector agent in sulfide flotation．Sodium diethyrldithiocarbamatre(DDTC)is a kind of effective sulphur flotation capture reagent．Most DDTC will react with sulfide IIlineraJ and elect the useJ’ul metal，and water residue DDTC Can cause great harm to the water enVironment．In the meanwhile，“Lead—zinc industry emission standards”(GB25466．20 1 0)implemented in 20 1 2 has tngher requirements to control the water pollution of Pb．Zn flotation waStewater．h order to effectively remove the residual DDTC in the environment，it is very important to explore its degradation behavior and mechanism This study used ozonation methods to treat the DDTC in simulation waStewater．The migration characteristics of carbon，sulfur and nitrogen in simulation、vaStewater were studied．The products of ozonation were analyzed．In the meanwhile，the 070ne oxidation degradation pathways and mechanisms of DDTC Was studied． Firstly，the experiment investigated the decomposition of 1 00 mg／L DDTC simulation wastewater by 5 g／h of ozone．The results demonstrated that after 1 5 r11in．the removal rate of DDTC could reach to 1 00％．However，the removal rate of TOC were 20．79％．It is shown that DDTC is not mineralized completely in the ozonation process，锄d generated small stable molecule organic matter in water．The pH in simulation wastewater was decreased from 8．47 to 3．1 8． Secondly,the migration characteristics of carbon，sulfur and nitrogen in DDTC dur访g 070natlon were analyzed by TOC analyzer,Ion Chromatography and methods for chemical analysis．When