多壁碳纳米管负载tempo催化剂的制备及其在醇氧化中的应用化学物理化学专业论文.docxVIP

中文摘要中文摘要 中文摘要 中文摘要 醇氧化反应所得的产物，如醛、酮等都是重要的工业原料，同时 也是重要的有机合成中间体，在醇氧化催化体系中，发展绿色、温和、 经济且具选择性的高效催化剂体系一直受到广泛的关注，其中可简单 回收和重复使用的固载氧化催化剂一直都是研究的热点。 本文介绍了碳纳米管作为催化剂载体的应用和催化剂TEMPO在 醇氧化催化研究中的应用两个方面的研究进展。碳纳米管载体稳定的 热力学结构，大的比表面积和易化学修饰的特性都表现出它可以作为 一个优良的有机小分子催化剂载体，本文通过两种简单的化学修饰方 法将TEMPO以共价键键和方式负载到多壁碳纳米管(M啪s)上， 得到一种新型固载TEMPO催化剂，M姗盯s．TEMPO，并考察了该催 化剂在醇氧化反应中的应用，运用FT-IR,TGA等表征手段对催化剂进 行了表征。 研究表明催化剂MWNTs．TEMPO在伯醇氧化中有极高的催化 活性，与传统固载催化剂相比，既达到了传统固体催化剂可简单回收 的效果又可以像高分子负载催化剂那样在某些溶剂中具有良好的可 溶性。 关键词：碳纳米管，TEMPO，醇氧化 AbstractThe Abstract The products of alcohol oxidation，such aS aldehyde，alkone and other oxygenates，are important industrial raw materials and organic synthetic intermediates·The development of green,mild economy and lligllly selective catalytic system haS received the widespread attention in alcohol oxidation catalysis，the eaSy recycled and reused solid supported catalysts is one of the research focus． In this article，we introduced the research developments of two aspect that the application of carbon nanotubes m)used as catalyst supports and the application of catalyst TEMPO in alcohol oxidation．Carbon nanotubes(CNTs)seemed to be promissing candidates for use as heterogeneous catalyst supports for small molecule oganic catalysts due to their thermal stability,big surface and they Can be chemical modified e豁ily．Here TEMPO is tethered to the multi．walled carbon nanotubes (1V[WNTs)through a simple chemical—covalent method，resulting in a MWNTS。supported organic catalyst．And then examined its catalytic activity in alcohol oxidation，the catalyst was also characterized in detail by FT-IR,TGA etc．techniques．The resarch demonstrated that the catalyst exhibited high catalytic activity in primary alcohol oxidation．Compared with traditional solid supported catalysts，the MWNrs—TEMPO carl run a reaction under homogeneous catalysis conditions like polymer-supported Abstractcatalyst Abstract catalyst and then to recover the catalyst as if it were bound to an insoluble Keywords：carbon nanotubes，TEMPO，alcoho