表面分子印记聚合物的制备及其在农残检测中的应用无机化学专业论文.docxVIP

搏要分子印记聚合物可以实现对痕量农药残留分子的高灵敏度和高选择性的检测，为 搏要 分子印记聚合物可以实现对痕量农药残留分子的高灵敏度和高选择性的检测，为 农药的残留检测提供了新的途径。 关键词：分子印记技术；层层自组装；荧光功能单体；农药残留 Ⅱ A侉STRACTABSTRACT A侉STRACT ABSTRACT Molecular imprinting technique(MIT)is becoming increasingly recognized as a powerful technique of preparing synthetic polymers that contain tail．made recognition sides for certain molecules．The most significant advantages of molecularly imprinted materials are high affinity and hi【gh selectivity to analyte，mechanical／chemical stability,low cost and ease of preparation,usage of long lifetime，and hence have attracted extensive research interests due tO the potential application in purification, separation,immunoassay,biomimics，chemical and biological sensors，catalysis， enviro·nment detection，drug release and other relevant fields for its predetermination， specificity and practicability of molecule recognition． The research described in this thesis gives a brief overview of the development of novel strategies facilitating advanced understanding of the fundamental principles governing selective recognition of molecularly imprinted polymers，and discusses the problems and challenges that molecular imprinting technique meets with at present． Traditional molecular imprinting techniques often produce the polymer materials exhibiting low binding capaci锣and slow binding kinetics due to low density of effective recognition sites，limiting their use in sensors．As all alternative to these approaches，nallo—sized imprinting materials may provide a potential solution to these difficulties due to their extremely high surface．．to．．volume ratio which lead to the recognition sites to locate at the surface and in也e proximity of materials surface．SO they have a high affinity and fast binding kinetics．It’S a wise strategy to prepare molecular imprinting materials at the surface of support cores through a simple modification．ms thesis aims at pesticides recognition and detection．Taking advantage of the LBL technique，silica core．shell i