氮化铝颗粒增强铝基复合材料的腐蚀行为研究材料学专业论文.docxVIP

卜海交通大学博f。学位论文 卜海交通大学博f。学位论文 摘爱 为了提高6063／AIN。的耐蚀性能，本文分别对其进行了酸性和碱性条件下的阳极 氧化处理。用电化学阻抗、极化方法、开路电位和点滴试验对它们的耐蚀性能进行了 评价。结果表明：由于在碱性条件下，增强体AIN颗粒水解，对阳极氧化膜层中的多 孔层起着充填作用，生成的阳极氧化膜层明显要优于酸性条件下生成的阳极氧化膜 层。碱性阳极氧化膜层的防腐效果与碱性溶液中的NaOH浓度有关，当所NaOH浓度为 0．7N时，防腐效果在本试验中最好。另外，对碱性条件下生成的阳极氧化膜层分别 进行重铬酸盐封孔处理和热水封孔处理发现，前者比后者的耐腐蚀性能更好。对它们 的结构观察表明，热水封孔处理的表面比较粗糙，孔隙较多，其密实程度明显不如用 重铬酸盐封孔处理。这也是热水封孔处理表面的耐蚀性能不如重铬酸赫封孔处理表面 的主要原因。 关键词：腐蚀，腐蚀防护，AI／AIN。，阳极氧化，电化学阻抗谱 ．P海交通丈学博十学位论文 ．P海交通丈学博十学位论文 ABSTRACT STUDY oN CoRROSIoN BEHAVlOR OF ALUMINUM NITRIDE PARTICULATE REINFoRCED ALUMINUM MATRIX CoMPoSITE ABSTRACT Aluminum-matrix composites containing high volume fraction of／kin particles have been of interest for some time in many sectors of industry for their attractive thermal properties：high thermal conductivity and low coefficient of thermal expansion．It is now appreciated that the potential for this kind of composite in electronic packaging is very broad．However,the introduce ofthe reinforcement A1N particle affects corrosion behavior ofAI／AINp just like other metal matrix composite，，and at the．戤l／lle time A1N particle easily hydrolyzes．which makes corrosion behavior of AⅪ心吼complicated．To deal with it, certain factors which influence corrosion behavior of AI／AINp and corrosion mechanism were systematically studied in this work．Based On it，an alkaline anodizing process for A1／AINp was researched，by which corrosion resistence of AI／A1Np Was effectivly enhanced． Research devoted to corrosion behavior ofAI／AINp has been spare in comparison with research on mechanical and thermal properties．The influence ofintroduce ofAIN particles， the pH value of the solution and hydrolysis of A1N particles on corrosion behavior of 6063／AINp were investigated by potentiodynamic polarization and electrochemical impandance spectroscopy(EIS)in this work．And at the same time，the general corrosion behavior of 6063／A1Np waS studied fBrther by immersi