uv固化体系中颜料表面改性对材料性能的影响材料学专业论文.docxVIP

⑧浙江工誓女孽硕士学位论文 ⑧浙江工誓女孽 硕士学位论文 化，存在着明显的界面耦联现象。表面改性不仅可以降低颜料表 面吸附的空气所造成的固化效率下降的趋势，而且可能是在UV 被颜料吸收之前就实现有效的引发剂UV吸收竞争，引发聚合反 应，提高固化效率。 3．对于逐层固化紫外光快速成型材料，体积颜料纳米Si02经过适当 的表面改性，材料的性能：力学性能、耐磨性能有所改善。颜料 表面改性后，扫描电镜分析表明，材料增强、增韧，且颜料分布 相对比较均匀；金相显微镜表明，材料硬度明显提高；通过DSC 分析表面，材料的Tg提高了。经过再次包覆改性，改性效果较好。 其中德谦ADP的改性效果最为理想(较之未改性的，磨损率减小 了近O．5％，玻璃化温度提高了近5℃，拉伸强度提高了近15MPa)。 这说明紫外光固化体系中固体颜料表面改性来提高或改善含颜 料UV固化材料是可行的。研究结果对含颜料光固化材料的研究开发 乃至光固化体系填料的使用等都具有积极意义。 关键词：紫外光固化材料，颜料，表面改性，界面，快速成型 EFFECTS EFFECTS OF THE SURFACE MoDIFIED PIGMENTS ON PROPERTIES oF MATERIALS IN UV CURING SYSTEM AB STRACT Curing of pigmented systems has been one of the challenges in the field of UV curing．This dissertation deals with the properties of UV cured materials with pigments(color pigments and bulk pigments) modification．These properties mainly include the rheologic property, the curing time，the gloss，the mechanical properties，the friction properties and the thermal stabilities of the materials etc．This dissertation also illuminated the mechanism of the pigments surface modification in the UV curing system， by the X-ray diffraction analysis (XRD)，SEM，DES，thermal analysis(TG,DSC)，metallography microscope．The results showed that： 1．The curing rate and the gloss were improved after the pigments were properly modified(e．g．In the case of TEA，the curing rate of blue pigmented UV curable coating(1 25 grn)could be improved greatly (from (from 45s to 14s))． 2．The obtained results have shown that through the modification of the pigment，the atmosphere layer absorbing on the surface of pigment plays an important role in hindering UV curing．In addition，there obviously exists the interface coupling effect between the pigment and the binder via the modifier．With the ESEM，it was found t11at the wetting cability of the pigment was improved and the binding between pigment and resin was strengthened after the modification of pigment． The EDS data showed an obvious enrichment of O—containing group of modification agent(-OH)in the interface and