超分子复合膜在电分析上的应用及现场电化学显微光谱法初步研究分析化学专业论文.docxVIP

英文摘要Abstract 英文摘要 Abstract In this paper,the cellulose acetate／Prussian blue composite film biosensor for determination of hydrogen peroxide was described．The cellulose acetate covered Prussian blue modified glassy carbon electrode was fabricated aS a novel hydrogen peroxide biosensor．The modified electrode showed all excellent electrocatalytic activity for H202 reduction in neutral solutions．H202 was detected amperometrically in pH7．0 phosphate buffer solutions at all applied potential of一0．2 V(VS．SCE)．The response current was proportional to the concentration of H202 in the range of 1．0× 10。5 mol／L to 2．5×10‘4 mol／L with the detection limit of 2．2×10缶mol／L at a signal to noise ratio 3．In addition，the modified electrode performed an excellent operational stability． Also，a submonolayer of 3-mercaptopropionic acid(3-MPA)was adsorbed on a polycrystalline gold electrode further reacted讯th poly(amidoamine)(PAMAM) dendrimer(generation 4．0)to obtain a film on which PMo I 2 was later coordinated to afford a mixed electrocatalytic layer．On the basis of the electrochemical behaviors， atomic force microscope(AFM)and X—ray photoelectron spectra(XPS)，it is suggested that the PMol2 nanoparticles are located within the dendritic structure of the surface attached PAMAM dendrimers．The protonated microenvironment provided by PAMAM not only promises the higher electroactivity of PMol2 at pH4．0，but also improves its stability．It has been shown that the PAMAM—encapsulated phosphomolybdate performed a high electrocatalysis to the reduction of S20。2‘and H202 in weak acidic aqueous solution(pH4．0)．It is promising that the phosphomolybdate—PAMAM complex might be used in electroorganic synthesis under moderate conditions or in developing electrochemical sensors for use in weak acidic solutions． Other，we introduce the chemical imaging，the calssification，the application of spectral imaging and the research of electrochemical spectral imaging．We got the II 英文摘要image 英文摘要 image of bare and modi