基于CFD的臭氧传质模型的研究环境科学与工程专业论文.docxVIP

Abstract Abstract 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - III - Abstract Ozone, as a disinfectant, has a very strong ability to inactive on almost all bacteria, viruses, and fungi. Giardia and Cryptosporidium can be inactived by ozone, too. So, ozone disinfection has gain a lot of attention. Bromate which can cause cancer at low dosage, could be generated when contains bromide ions. Therefore, ozone disinfection is faced with how to optimize the efficiency of sterilization and disinfection by-products of the problem. At present, the effects of ozone disinfection is evaluated through CT10,but CT10 methods is too conservative, resulting in excessive dosage of ozone, increase disinfection by-products. In order to ensure that disinfection efficiency, at the same time, control the generation of by-products, it would take as much as possible so that the ozone contact tank of the concentration of ozone distribution. Bubble column is most common in ozone contact, ozone mass transfer co-efficient is a critic factor in determining ozone distribution in water. To the problem above, we will couple ozone mass transfer and decay kinetics, dynamics disinfection, bromate formation dynamics, use of CFD (Computational Fluid Dynamics, CFD)to simulation bubble-column ozone contact, base on bromate formation mechanism, optimize design ozone contactor, solving the security problems of ozone disinfection. This project has been the support of the National Natural Science Foundation. This paper construct ozone mass transfer CFD model based ozone mass transfer and ozone decay kinetics, establishment of the foundation for the next step. In this paper, we have determined ozone mass transfer coefficient and ozone decay coefficient in bubble column, with gas-liquid mass transfer theory. The volumn ozone mass transfer co-efficient is 0.13, ozone decay co-efficient is 0.51, and use this kinetic parameters, the application of CFD (computational fluid dynamics) model of multi-phase flow to model bubble