介孔分子筛MCM-41吸附CO2研究-工业催化专业论文.docxVIP

ABSTRACT The carbon dioxide（CO2）adsorbents was prepared through impregnating the synthesized MCM-41 with polyethylenimine (PEI). MCM-41, the supporter of PEI, can be synthesized by different methods. In this paper, we used different preparation ways for MCM-41 obtaining variant structure and investigated how mesoporous structure of MCM-41 impacted the CO2 adsorption capacity. The resultant samples were characterized by small angle X-ray power diffraction (XRD), High resolution transmission electron microscope (HRTEM), N2 adsorption/desorption, thermal gravimetric analysis (TGA) for the CO2 adsorption performance. At 1131m2g-1 of BET surface area in MCM-41 and 50 wt. % of PEI loading in MCM-41, the highest CO2 adsorption capacity of 232.1 mg/g-PEI was obtained. MCM-41 mesoporous molecular sieve has high water thermal stability and single pore canal, and has large specific surface area. Through loaded organic amine, it has higher selectivity and higher adsorption quantity than common solid adsorbent. Using channels internal classification structure can improve the organic amine dispersion and the adsorption of carbon dioxide. This paper focuses on the research the preparation of MCM-41 of which template is removed partly by chemical method and loaded PEI as solid adsorbent. Adsorbent is characterized by XRD, FT-IR, TEM, BET TG, and we research the influence of template on PEI dispersion and carbon dioxide adsorption. MCM-41 50% load the adsorption quantity PEI get CO2 than MCM-41 50% load PEI sample increased by 12.6% to 131 mg/g. 50% load PEI and MCM-41 75% load PEI adsorption basic consistent, but the former PEI in the CO2 adsorption for 262 mg/g, while the latter for 175 mg/g, adsorption increased by 50%. It indicated that the duct internal, since there are filamentous micelle and the formation of classification structure increased the organic amine dispersion, thus increasing CO2 absorption. KEY WORDS： Mesoporous molecular sieve; Mesoporous structure; M