介孔分子筛增强阻燃聚双环戊二烯-高分子化学与物理专业论文.docxVIP

摘要 密度，增强了两相的界面相互作用，有效地增强了材料的力学性能；而 Method 3 材料由于 SBA-15 拥有更大的孔道尺寸使更多的分子链进入孔道，因此增强效 果更明显。 另外分析对比了 Method 1~Method 4 四种 PDCPD/SBA-15 复合材料及纯 PDCPD 聚合物的阻燃性能。结果表明，与纯 PDCPD 相比，Method 3、Method 4 两种方法制备的材料燃烧速率下降，固体残余量增大，生烟密度减小，成炭更明 显，材料阻燃性能得到显著提升，其中 Method 3 材料阻燃性能提升效果更明 显。其阻燃机理是由于 SBA-15 负载催化剂之后，其纳米级孔道能有效地限制孔 内聚合物链的自由热运动，同时其介孔孔壁具有极好的耐热性和绝热性，能延缓 孔内的热分解及分解产物的释放；而 Method 3 材料由于 SBA-15 孔径更大，孔 内受限的聚合物链更多，因此阻燃效果更强。 关 键 词：介孔分子筛，PDCPD/SBA-15，催化剂负载，增强，阻燃 论文类型：应用基础研究 II 摘要 Subject: Reinforcing and Flame-retardant Effects of Mesoporous Molecular Sieve on Polydicyclopentadiene Specialty: Polymer Chemistry and Physics Name: Liu Xian-jun Supervisor: Associate professor Lu Chang ABSTRACT Mesoporous molecular sieve has attracted a great deal of interests for its particular characteristics, such as large internal surface area, uniform framework and easily controlled pore diameter. Thus, some of their applications including catalysts, sorbents, separating materials and reinforcing material of polymer are expected. In this paper mesoporous molecular sieve was employed to enhance the performance of PDCPD (polydicyclopentadiene). The perpared methods of PDCPD/mesoporous molecular sieve composites and their mechanism were studied. SBA-15 mesoporous molecular sieve was synthesized by hydrothermal synthesis, and the best reaction condition of in-situ polymerization of DCPD (dicyclopentadiene) compounding with SBA-15 was investigated. Four kinds of methods were employed to prepare PDCPD/SBA-15 composites by self-mading RIM device, which are in-situ composite of: DCPD and SBA-15 (Method 1), DCPD and SBA-15 modified with couple reagent (Method 2), DCPD and SBA-15 supported catalyst (Method 3), DCPD and modified SBA-15 supported catalyst respectively (Method4). Four kinds of PDCPD/SBA-15 composites (Method 1 to Method 4) were characterized and tested by XRD, TG, and determination of cross-linking degree. The results showed that for the composites prepared by methods 1 and 2, the polymer