介孔分子筛SBA-15中Pd金属纳米材料的制备表征及其CO氧化反应-化学工艺专业论文.docxVIP

- - PAGE VII - ABSTRACT This discussion focus on the synthesis of the bimetallic nanomaterial and Pd nanomaterial within the uniform channels of the mesoporous SBA-15 via the glow discharge plasma. Then the CO oxidation is applied for the test of the catalysis performance of these material. In order to characterize the physical and chemical performance of the synthesized materials, a serials of techniques are employed, including transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), N2 physical adsorption-desorption, temperature programmed oxidation (TPO), Fourier transform infrared spectroscopy (FT-IR), UV visible spectroscopy (UV-vis), CO chemical adsorption, energy dispersive x-ray spectroscopy and STEM. The bimetallic noble nanomaterial have been synthesized within the ordered channels of the silica SBA-15 through the wet impregnation method via the glow discharge plasma reduction. The TEM results show that the synthesized material have the particular morphology: Au-Pd bimetallic nanoparticle, Au-Ag nanowire, Ag-Pd nanowire and Pt-Pd nanorod. And the results of the EDX and STEM indicate that in the material Au-Pd and Ag-Pd, the metal elements have a particular distribution. The significance of this new synthesis method through the glow discharge plasma is that it is simple, facile, green and economic. The highly dispersed Pd nanoparticles were synthesized via the glow discharge plasma, and then was further calcined in O2 atmosphere and subsequently in H2 atmosphere. The glow discharge plasma can reduce the Pd2+ into metallic Pd completely. The further treatment leads to some changes of the Pd surface. The CO drift indicates that there are some similarities and differences in the size, valence state, the bridge adsorption strength and the CO adsorption enthalpy between two samples. And these aspects were verified by the results of CO oxidation, TEM, XRD, CO chemisorption, the calculation of TOF and XP