介孔二氧化硅的合成、改性及其在分析中的应用研究-高分子化学与物理专业论文.docxVIP

ABSTRACTMesoporous ABSTRACT Mesoporous silica materials with ultra-high surface area，large pore volume，controlled shape and size have attracted wide attention because of their application in biomedicine．With the development of biological materials， higher requirements are put forward to design and synthesize di fferent structures and funcationalized mesoporous materials．In this dissertation， studies on mesoporous silica with different morphology were carried out．The main contents discussed were as follows： (1)SBA-1 5 was synthesized successfully by the acid catalysis of tetrathoxysilane(TEOS)in the presence of block copolymer E020P070E020 (P 1 23)as template．On this basis，mesoporous silica vesicles were synthesized by adding trimethylbenzene(TMB)as a swelling agent．The reaction conditions，such as the ratio of TMB／P 1 23，the concentration of hydrochloric acid and the temperature of hydrothermal treatment，were optimized． Meanwhile，Amino mesoporous silica vesicles were prepared successfully by grafting with 3-aminopropyltrimethoxysilane(APTS)．The large pore mesoporous silica vesicles modified with amino group were expectable to find their application in the field of biological macromolecules． (2)The vesicular or ordered meso-structured silica materials can be obtained firstly by just changing the time interval between trimethylbenzene and E020P070E020．The process of materials structures change was monitored III by by XRD and TEM technology．Meanwhile，a reasonable explanination with the help of“cooperative vesicle templating”(CVT)and“cooperative self-assembly mechanism’’(CFM)was proposed to explain the formation of vesicular or ordered meso-structured mesoporous silica． (3)Monodispersed new colloidal mesoporous silica was synthesized by the use of the base triethanolamine(TEA)in prescence of cationic surfactant． Based on its good adsorption performance to phenolic compounds， as-synthesized colloidal mesoporous silica(un—CMS)was used to separate and e