基于功能离子液体聚合物的制备及其在CO2固定当中的应用-高分子化学与物理专业论文.docxVIP

3.结果与讨论····································································································27 3.1 离子液体及聚离子液体的合成······························································27 3.2 离子液体的热性能··················································································28 3.3 离子液体[EEIM]BF4 的单晶衍射 29 3.3.1 晶体分析····························································································34 3.3.2 [EEIM]BF4 电化学性质的测试 35 3.4 聚离子液体性质的表征···········································································36 3.5 聚离子液体分子量的测定·······································································38 3.6 聚离子液体的扫描电镜···········································································38 3.7 功能离子液体、聚离子液体对二氧化碳的吸收性能·····························39 3.7.1 试验方法·····························································································39 3.7.2 离子液体[BMIM]PF6 对 CO2 的吸收 39 3.7.3 离子液体、聚离子液体吸收 CO2 的动力学 40 4.本章小结········································································································41 第三章 功能离子液体催化二氧化碳环加成反应的研究········································42 1 引言················································································································42 2 实验部分········································································································42 2.1 原料和试剂······························································································42 2.2 实验原理···································································································42 2.3 实验方法··································································································43 2.4 二氧化碳与环氧化合物的环加成反应··················································43 2.4.1 [HHIM]Cl 催化二氧化碳与环氧化合物的环加成反应 43 2.4.2 [EEIM]Cl 催化合成二氧化碳与环氧化合物的环加成反应 46 3．本章小结·························································································