碱性钙基膨润土的制备机理探索及其应用研究-化学工程与工艺专业论文.docxVIP

3：40，分散剂环己烷50．00 3：40，分散剂环己烷50．00 mL，反应3 h。制得的苯甲酸土有机含量为27．10 ％，接近理论值。结构表征表明，苯甲酸根已插入膨润土的层间，使产品 的层间距扩大，晶型更加完整。碱性钙基膨润土的活性氢氧根基本都参与 了反应，膨润土由亲水性向疏水性转变。 碱性钙基膨润土的开发，在其它种类的高酸价油脂精炼以及多种有机 酸土的制备等方面还有着更广阔的应用前景。 关键词：碱性钙基膨润土机理茶油精炼有机酸膨润土 Ⅱ STUDIES STUDIES oN PREPAR ATIONⅧCHAl汛SM AND APPLICATION OF ALKALINE Ca．BENT ABSTRACT Alkaline Ca-bentonite is a new kind of layered materials；it has great practical value and bright market prospect because of its special anion exchange capability．For the purpose of knowing alkaline Ca-bentonite further and broadening its application，this paper had searched its preparation mechanism and proposed two kinds of application on grebe refining and composed organic acid bentonite． Alkaline Ca-bentonite was prepared by activated clay and calcium hydroxide by the half-dry process．The process，which layer-spacing growing gradually,owed to the together action of calcium hydroxide move in layer and the water in layer vapor．It was concluded that drying had a big influence on reaction because its vapor control the degree of calcium hydroxide move in layer The reaction carried out like the mechanism Bent-H+Ca(OH)2—— Bent-Ca(OH)+H20． The refining technology of camellia oil using modified bentonite without water was investigated．Camellia oil Was bleached by activated clay and then deacidified by alkaline Ca-bentonite while it was degumed simultaneously in this two processes．Conditions of the bleaching and deacidification processes 111 were were optimized．The results indicated that the refining technology Call meet the standard of bleaching，deacidification and degumming of camellia oil，and can decrease the peroxidation and the content of the impurity in some extent．It Was concluded that the present technology simplifies the refining process of camellia oil and decreases cost in a great extent． The organic modification of Alkaline Ca-bentonite used hexamethylene alkyl which is not polarity as dispersant．The modification method Was ebullience，cireumfluence and d