碱金属醇（酚）盐的合成及其在二烯烃阴离子调节聚合中的应用-高分子材料专业论文.docxVIP

碱金属酵(酚)盐韵合成及其在二烯烃阴离子调节聚台中的应用摘要 碱金属酵(酚)盐韵合成及其在二烯烃阴离子调节聚台中的应用 摘要 本论文采用廉价易得，安全性强的原料，通过实验，确定了几种碱金属醇(酚)盐 (ROK)的最佳合成方法、路线和工艺条件。 考察了不同ROK在甲苯、乙醚、四氢呋喃(Ⅱ{F)及二乙二醇二甲醚(2G)等不 同溶荆中溶解能力，又考虑到溶剂对聚合物结构的影响，以及工业化的难易程度等方面， 最终确定了ROK的最佳溶剂为1HF。 在n-BuLiPROK／二．甲苯／2GI--烯烃阴离子调节聚合体系中，考察了不同ROK对二烯 烃阴离子调节聚合的影响。结果表明，ROK作为阴离子调聚助引发荆不仅对丁二烯有 明显的调聚效果，而且对异戊二烯的调聚效果也很明显。此五种ROK的调聚能力区别 不大。 本论文考察了不同K／Li对单体转化率、调聚物分子量、分子量分布以及微观结构 的影响。结果表明，随着K／Li的增大．单体转化率变化不大，都能达到100％：聚合物 的链转移次数增大，分子量降低，分子量分布加宽，聚T--烯调聚物的1，2．结构含量下 降。聚异戊二烯的l，2一结构含量下降，3,4．结构含量升高。 综合合成工艺、溶解能力、调聚能力及价格等几方面因素，确定了最有工业化前景 的ROK。 关键词：碱金属醇盐：碱金属酚盐；丁二烯；异戊二烯；阴离子调节聚合 壁垒墨壁!堂!苎塑鱼堕墨墨垄三塑丝塑塑三塑蔓墨鱼!竺堕旦Abs仃act 壁垒墨壁!堂!苎塑鱼堕墨墨垄三塑丝塑塑三塑蔓墨鱼!竺堕旦 Abs仃act In this paper,several kinds of alkali metal alkoxides and alkali metal aryloxides(ROK) were synthesized from cheap and safe raw materials．ne synthesis technology was determined． The solubilities of ROK in several different solvents such as toluene，ether,THF and 2G Were studied．Considering the influence of solvent on the microstructure of telomers．THF was determined to be the best solvent． In the system of n—BuLi／ROK／xylene／2G／olefin．the influence of ROK on diolefin anionic telomerization was investigated．越n the result shows that the difference between butadiene system and isoprene system was little．The influence of ROK on olefin anionic telomerization was obvious not only in butadiene system but also in isoprene system． Conversions of monomer,molecular weight，molecular weight distribution and microstructure of telomers were studied with different K／Li．The result shows that the conversion of monomer changes little wim K／Li．When K／Li rises．the molecular weight of telomer descends，and the molecular weight distribution gets wide．K／Li Can affect the microstructure too,When K／Li rises，the content of 1,2-unit descends in butadiene system．In isoprene system，the content of 1,2-unit descends and the content of3，4-unit rises． Considering of synthesis technology,solubility,telomerizing ability and price，the best ROK was determined． Key wor