焦炉气综合利用技术开发-化学工程专业论文.docxVIP

北京化工大学硕士学位论文 北京化工大学硕士学位论文 万方数据 万方数据 万方数据 万方数据 11 ABSTRACTTECHNOLoGICAL ABSTRACT TECHNOLoGICAL DEVELoPMENT oF THE COMPREHENSIVE UTILIZATIONG OF COKE oⅦN GAS ABSTRACT Methane was an important clean energy and had wide appl ication value． Hydrogen had an irreplaceable role in metallurgy．coal chemical industry and other industries．Coke oven gas contained rich methane and hydrogen．and the extraction of methane and hydrogen was an important way for high value use of coke oven gas．It could reduce gas pollution．coal consumption and oil impolrts，and have important market values． After systematical literature review,based on the study of the characteristics of the coke oven gas generated from coal application process of Risun company,a technical scheme of methane／hydrogen extraction from coke oven gas Was selected．and the reIated suitable operation conditions was also be choosed．Based on these information，we took 41 04Nm3／h coke oven gas as a special case，designed and improved the technology of methane and hydrogen extraction process，and built up the production flowsheet which contains gas prctreatment， compression， conveBlon，pressure swmg adsorption and other processes．The final operation results showed that the quality of SNG iS satisfied and the purity of H2may be more than 99．9％which can be meet the need of technology design．A excellent economic benefits for the company was obtained． KEY WORDS：coke oven gas，PSA，natural gas，hydrogen 北京化工大学硕士学位论文 北京化工大学硕士学位论文 万方数据 万方数据 IV 目录目录 目录 目录 第一章概述 1 l，l研究背景 1 1．1．1公司基本概况 1 1．1．2项目研究背景 1 1．1．3项目建设的必要性和意义 3 1．1．4合作开发单位概况 ．4 1．1．5项目实施的优势 5 1．1．6项目的研究范围 5 1．2技术调研结果分析 6 1．3市场调研分析 6 l3．1天然气 ．6 1．3．2氢气 ．8 l，3．3世界天然气资源的分布与市场状况 9 1．3．4我国天然气市场分析 一1 0 1．3．5地区天然气市场分析 ．1 1 1．3．6我国东部地区天然气价格分析 ．．1 5 第二章焦炉气制天然气工艺方案设计 17 2．1原料、产品控制指标 1 7 2．1．1原料控制指标 ．．1 7 2．1．2产品SNG控制指标 l 7 2．1．3产品氢气控制指标 ．．1 7 2．2生产规模 。l 8 2．3工艺方案的选择 ．1 9 2．3．1氢气提取技术的选择 ．1 9 2．3．2甲烷气提取技术选择 ．2 l 2．3．3焦炉煤气预处理脱油脱萘器选型 2 l 2．3．4焦炉煤气压缩机选型 ．22 2．3．5变换催化剂选型 一22 2．3．6 PSA工序吸附剂再生方法选择 ．23 万方数据