焦化石脑油加氢装置产品不合格的原因分析-化学工程专业论文.docxVIP

焦化石脑油加氢装置产品不合格的原因分析耱翠舔≤纯学暑程) 焦化石脑油加氢装置产品不合格的原因分析 耱翠舔≤纯学暑程) 指导老师：杨向平(教授) 摘要 浆厂大焦化装置歼工后，大小焦化汽油及焦化凝绒油作为加氢装 置的遴料，所得产品不合格。为查找原因，本工作对装置原料进行跟 踪分据。痰客锻摆：款缀成分辑、硫含曩分榜、馁程分摄、浚徐分板、 硅含鬃分析、硫形态分布分析．同时对装置卸出催化剂进行了采样分 辑，凌容有：失潺篷纯裁静锈纯往覆分褥，莠生镗纯麓豹穆纯缝震分 析及灞性评价，加氢容硅剂的评价，级配催化剂的评价。 对原科静跟踪分析得甾：原料油静硫含爨、硅含鼗、漠债鄱眈较 高，缀料浊质量变差是加氢生成油不会格的一方面原因；装鬣处理量 变大，焦化汽油的千点控制不合理是粥一方面原因。对加氢催化剂的 分拆褥窭；建、铗是搜攫纯裁失溪豹麦要原霆。嚣恁建议采弱艇氢綮 制剂的上面依次加入HPS-02容硅剂、LH-04脱铁保护剂的装填方式， 兔掷制催证裁失活的躲决方案。 关键测：加氢精制，焦化石脑油，催化剂 n Analysis Analysis of Unqualified Product From Coker Naphtha Hydrofining Unit SUN Cui-lin(Chemical Engineering) Directed by ProfessorYANG Xiang-ping Abstract Hydrogenated oil from naphtha hydrofining unit was the feedstock for ethylene cracking unit sometimes．All ofthe coker gasoline and condensation product wcre used as the charge-in ofthe hydrogenation unit after the”bigger coking unitwas on stream。But its product was not acceptable in quality． To find out why the product was unaccepmble and to assure that the unit is in a long pedod of operation,following work was made,such as the analysis to the feedstock including the group component,the sulfur content, the distillation range,the bromine value,the silicon content,sulfur species distribution,and the analysis to the catalyst including the physicoehemieal properties ofdeaefivated catalyst，the physicochemical properties and activity rating ofregenerated catalyst． The results showed tllat the poorer quality feedstock added the content of sulfur and silicon in the gasoline frombigger coker’．In addition to above,the bigger throughput and absurd gasoline cndpoint control were reason resulting unacceptable product．The catalyst deactivation was nlade by silicon and iron。So we should adopt鑫loading type put HPS-2 silicon-holding reagent,HL··04 de-·iron reagent and protection reagent above the hydrofining agent． Keywords：Hydmfining，Cokernaphtha,Catalyst lIl 独创性声明本人声明所呈交的论文是我个人在导师指导下进行的研究工作及 独创性声明 本人声明所呈交的论文是我个人在导师指导下进行的研究工作及 取得的研究成果。尽我所知，除了文中特别加以标注和致谢的地方外， 论文中不包含其他人已经发表或撰写过的研究成果，也不包含