焦化废水的催化氧化法预处理工艺研究-环境工程专业论文.docxVIP

重庆大学硕士学位论文 重庆大学硕士学位论文 中文摘要 摘 要 本文以焦化废水作为研究对象，采用Ti02光催化氧化和Fenton试剂催化氧化 法对焦化废水进行预处理试验，考察此方法在处理焦化废水时的各种试验条件、 影响因素及处理效果，并探索Ti02光催化氧化和Fenton试剂催化氧化反应的过程 和化学机理。 研究发现，半导体光催化剂Ti02对焦化废水的光催化效果和Ti02的晶型有很 大的相关性，锐钛型Ti02对焦化废水的光催化效果明显优于金红石型Ti02；对锐 钛型Ti02进行高温处理后，发现温度对Ti02的晶型改变及表面结构影响较大，在 600℃高温煅烧下，Ti02的光催化活性有较大提高：并且催化剂的活化方式对处理 结果亦有较大的作用。 同时对催化剂H202+Fe2+(Fenton试剂)处理焦化废水的光催化活性进行了研 究。结果表明，Fenton试剂在条件适宜的情况下，催化活性很高，对COD。，的去除 率可超过80％。所以，试验选取Fenton试剂(H202+F92+)复合体系处理焦化废水， 考察了催化剂的配比、溶液初始CODcr值、pH值、光照时间、光强等因素对催化 活性的影响。 结果表明，本文的试验结果有助于进一步研究其他高浓度有机废水的光催化 处理的开发与利用。 关键讯焦化i№≤剂击光催妊作嘤理 重庆大学硬士学往论文 重庆大学硬士学往论文 英文摘要 ABSTRACT In this study,tar wastewater was as the object mainly discussed how to treat，and was treated by using Ti02 light catalyze oxidationFenton reagent catalyze oxidation treatment，the process and mechanism ofreaetion WaS searched also． The results showed that the effect that light catalyze oxidation treated妊匿 wastewater WaS related to the kinds of catalyze，and the result of experiment using Ti02 was better than mtile．Catalyze capability Was improved obviously after Ti02 was calcined at 550*(2，and the way ofcalcine had large actions for catalysis， Photo catalytic degradation of organic compound in tar wastwater was carried out with Fenton reagent(H202+Fe2+)，the following conclusion call be attained：when good condition，the system’s photo cataIytic activity was enhanced，but when adding to Ti02，the photo degradation efficiency decreased． Therefore，in the following experiments，Using Fenton reagent(H202+Fe”1 composite semiconductor幻treat tar wastwater，the influence of pH value，initial tetracycline concentration，light intensity，irradiated time，the proportion OfFe2++ Ti02，the volume Of Solution was respectively discussed．Under the Selected conditionsalmost more than up 80％of tar wastewater Was completely decomposed to C02arid H20。 Finallyt All these results would be helpful to further Study on t