焦化废水的复合絮凝处理研究-环境工程专业论文.docxVIP

武汉科技大学 武汉科技大学 硕士学位论文 第1页 焦化废水的复合絮凝处理研究 摘要 焦化废水是一种成分复杂的典型难降解有机废水，其中含有酚、氨氮、氰、苯、吡啶、 吲哚和喹啉等几十种污染物，污染物浓度高、色度高、毒性大，性质稳定。 本文采用投加絮凝药剂的方法处理焦化废水，通过对一种新型复合絮凝剂聚硅酸硫酸 铝铁(PAFSS)的制备和性能研究，结果表明：PAFSS是一种既具有较强的电中和能力， 又具有较优絮凝性能的无机复合型混凝剂，也是一种较好的处理焦化废水的混凝药剂。试 验确定了药剂的最佳投药量、最佳pH值等操作参数，并将其与其它几种单一及复合型絮 凝剂进行了比较，同时还通过正交试验考察了投加量和pH值之间的交互关系，并进一步 探讨了它的混凝作用机理。 试验中系统考察了絮凝剂种类，投加量和pH值等对焦化废水浊度，色度，COD和 U254的去除效果，用聚硅酸硫酸铝铁处理后的焦化废水浊度、色度、COD去除率可分别 达到99．03％，68．34％，89．60％的处理效果，最终出水浊度、COD都得到了很大的去除， 可降低到1．5NTU、65mg／L，达到国家二级排放标准，同时色度也得到了很大的降低。 关键字：焦化废水；絮凝剂；混凝；聚硅硫酸铝铁：交互作用 第1I页 第1I页 武汉科技大学 硕士学位论文 Study on Coking Plant Wastewater with Complex Flocculant Abstract Coking wastewater is a kind of typical refractory wastewater．There ale many pollutants in this wastewater,such as hydroxyhenzene，ammonia(usually recovered ammonium sulfate)， cyanogens，phenol，indole uinnoline and SO on．Components in the wastewater are very complicated．Concentration ofthe pollutants，its color and toxicity are high．And its character is stabilized． In the paper,complex flocculant PAFSS has been used to treat coking wastewater,including the preparation of PAFSS．Simultaneity,several simplex and complex flocculants were compared with it．As a result of the research，complex flocculant PAFSS which has good capabilities of neutralizing electric charge and flocculanting is effective to treat coking wastewater．In the experiment，the optimal dosage of flocculants and pH value have been ascertained，in the。 meanwhile，the interaction ofthe dosage and pH value also have been discussed：． The purification efficiency of turbidity,chroma and COD which have been measured with the different dosage and pH value are 99．03％，68．34％ and 89．60％respectively．Finally，the turbidity and chroma of the coking wastewater are only 1．5NTU and 65mg／L．This number is much lower than the national discharging standards． Keywords：coking wastewater；flocculants；coagulation；PAFSS；interaction 武汉科技大学 武汉科技大学 硕士学位论文 第1页 第一章前言 1．1选题背景’ 焦化废水是煤制焦炭、煤气净化