焦炭燃烧与气化过程的细观模拟-热能工程专业论文.docxVIP

华中科技 大学硕士 学 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Oxy-fuel combustion is a technology that can achieve zero CO2 emission for coal-fired power plant, having the advantage of engineering feasibility, non-technical barrier, pollutant coordination removing and so on. With the growing greenhouse effect, oxy-fuel combustion has becomes research focus at home and abroad. Combustion char acteristics of coal char under oxygen-rich condition is a compulsory basic study of oxy-fuel combustion, which can be studied by means of experimentation and model simulation. With the development of computer technology, numerical simulation is increasingly becoming an important means to study the combustion process. In this paper, a simple mathematical model for char combustion and gasification process under air condition is developed first, and it has been validated by using the experiment data. The model takes into account heterogeneous and homogeneous chemical reactions, multicomponent convection and diffusion inside the particle pores, as well as in the boundary layer. It also takes into account the physical properties of the gas mixture. Verification results show that the simulation results can agree with experimental results well. Then, the established model for char combustion and gasification process is used for a comprehensive simulation studies. The distributions of the main char acteristics during char combustion and gasification process are analyzed. And the effects of parameters such as temperature, particle size, pressure on the combustion and gasification process of char are also studied. Simulation results show that the model predictions for the distributions of the main char acteristics and the effects of the parameters are both in line with the general laws of physics. Finally, a kinetic model of char for oxy-fuel combustion is developed, and the simulation analysis for the coal char combustion under oxy-fuel condition is carried on. Simulation results show that during t