搅拌釜中离子交换树脂增强气液传质研究-化学工程专业论文.docxVIP

中文摘要化工过程强化是传统化工发展的重要方向之一。难溶气体参与的气液反应过 中文摘要 化工过程强化是传统化工发展的重要方向之一。难溶气体参与的气液反应过 程中，气液传质是反应过程的主要阻力，催化剂细颗粒能增强气液传质，提高反 应速率。 本文在容积为1L的搅拌釜中，对树脂颗粒催化作用下的异丁烯水合反应及 异丁烯在水一叔丁醇混合溶剂中的溶解度进行了实验研究。其中催化剂的粒径在 1．11 1．tm～300llm范围内。在0．74MPa、77℃实验条件下，考察了催化剂粒径、 固含率、叔丁醇起始浓度和搅拌转速对水合反应速率的影响。在70～90℃、0．60～ O．74MPa条件下，考察了异丁烯溶解度与温度及叔丁醇摩尔浓度的关系。 为了进一步研究催化剂颗粒对气液传质的影响，改变催化剂浓度，采用关联 式，计算得到了不同颗粒粒径下的液相总体积传质系数，与实验结果吻合较好。 对结果进行了分析。结果表明，小粒径颗粒对气液传质有增强作用，粒径越小增 强作用越明显；传质系数随粒径减小而增大，且粒径越小增大越快。 本文讨论了催化剂粒径不同时，水合反应的控制步骤。结果表明，对于小粒 径粒子(1．1llmd。17．69it m)，过程为表面反应控制。对于适度大的粒子 (53．68 u m山105 u m)，过程为内扩散控制。粒径大于105 p m时，过程为外 扩散控制。 关键词；催化剂颗粒，气液传质，异丁烯水合反应，控制步骤 ABSTRACT11地intensification ABSTRACT 11地intensification of chemical engineering process is one of the important developments that go beyond traditional chemical engineering．Frequently the 曲sorption rate ofsparindY soluble gas reactant to liquid phase limits the reaction rate． While the adsorption rate can be significantly enhanced by the presence of fine particles． The experiments of isobutene hydration reaction and isobutene solubility in mixed solvents of water and tertiary butyl alcohol were carried out in a stirred autoclave rfiactoL 111e volume ofreactor is l dmj．The size ofcatalyst particles ranges from 1．1l It m to 300 u m．The reaction rates catalyzed by various catalyst particle size，various catalyst solid contents，various beginning concentration oftertiary butyl， various stirred speeds were studied at 350Kand 0．74MP乱Isobutene solubility in water-alcohol mixtures has been correlated for alcohol concentration up to 2．0 kmoYm3 andtemperaturerangefrom335．15Kto 358．15Katpressureof0．74Ⅳ呼a． In ordelto stody the effect of catalyst particles on gas-liquid mass transfer in reaction system,the solid contents were changed．Tllc gas—liquid mass transfer coe伍cients in the presenc圮ofvarious pattiele sizes were obtained by using correlated equation。珏e results agreed with well the experimental data．r】je analysis of the results indicate that the volumetric mass transfer coe伍cient i