金属硫化物单分散纳米晶的制备和表征-材料物理与化学专业论文.docxVIP

浙江大学硕士学位论文 nm的高强度辐射峰为锰离子的发光，发光峰位并没有随着掺杂量改变而发生变 化。本征硫化锌的缺陷发光是由于硫空位等缺陷产生的浅能级上电子的辐射跃迁 造成的，硫化锌掺锰纳米晶的桔红色发光来自于锰离子的4T1．6AI电子跃迁的辐 射。 关键词；非有机金属前驱体合成路线；高温化学反应；硫化铜；硫铟铜；硫化锌掺 锰；胶体纳米晶；白组装 Ⅱ AbstractAbstract Abstract Abstract Due to their size and shape—dependent optical，electrical，magnetic,and catalytic properties,colloidal nanocrystals have been the promising building blocks for functional materials and devices，such as light emitting diodes，solar cells，telecommunication amplifiers,and biomedical fluorescent labels．Although the strategies of colloidal nanocrystals have attracted a special attention because of their fundamental role in their properties and applications，it was inevitable to u∞expensive，toxic，and environment- polluted organometallic precursor in the previous report．Moreover,the exploration ofnovel approach would be in favor of fabricating intriguing nanostructures with new properties Or application．Hence，a novel strategy has been developed to synthesize metal sulfide colloidal nanocrystals using inorganic salt as precursor．It is indicated that the above- mentioned approach is low-cost,simple，effective,environment friendly and general for the synthesis of metal sulfide colloid nanocrystals．Furthermore，the properties of the as— synthesized metal sulfide colloid nunocrystals have also been investigated．The main results achieved in this disquisition arc listed as below： (1)Monodisperse hexagonal CuS(covellite)and monoclinic Cul．7sS(roxbyite)disk-like nanocrystals were synthesized via high-temperature chemical reaction,respectively． Moreover,they could be self-assembled into the ribbon-like nanostruetures of copper sulfide by the face-to-face stacking along[001】direction under the certain condition． On the different substmte such as carbon film or silicon wafer,the stacking angle ofthe disk-like copper sulfide nanocrystals is different．It was flLrther indicated that Van der Waals force caused by rich sm缸condition(special crystallographic orientation ofCuS nanocrystals)，