金属硫化物及其碳修饰在染料敏化太阳能电池对电极中的应用-材料科学与工程专业论文.docxVIP

Abst陀ctAbstract Abst陀ct Abstract Due to their low cost，easy fabrication and excellent performance，dye-sensitized solar cells∞SSCs)have attracted widely academic and industrial attentions．The counter electrode(CE)is an important component of DSSC．Their price and performance directly affect the cost and photovoltaic efficiency of the cells． Conventionally,noble metal platinum is employed as CE．Platinum electrode possesses hi曲electrocatlytic activity for Is。reduction，superior conductivity and chemical stability．However,rare storage and hi曲price of platinum impede large-scale production of DSSCs．Therefore，the exploration of non—Pt and efficient electrode materials is significant for industrialization of DSSCs．The main work in this thesis is to develop several efficient and non-Pt electrode materials，and investigate their electrocatalytic properties．The content is aS follows： (1)A non—template method is proposed to prepare nickel sulfide with different phaSe，and the electrochemical properties of these nickel sulfides aS the counter electrode materials for DSSCs are investigated systematically．Via adjusting the molar ratio of Ni／S in the reactions，hexagonal NiS and cubic NiS2 hollow spheres were synthesized．The specific surface areas of NiS and NiS2 hollow spheres are obtained quantitatively by BET test．The results show that the specific surface of NiS2 is nearly twice aS large aS that of NiS．The electrochemical analyses demonstrate that NiS2 electrode exhibits superior electrocatalytic activity，higher electric conductivity and lower diffusion resistance of Is。ions．As a consequence，the DSSC with NiS2 CE generates higher power conversion efficiency(7．1 3％)than that with NiS CE(6．49％)． (2)Hollow spherical NiS／NiS2 composite is synthesized by one‘step solvothermal route．The electrochemical analyses show that NiS／NiS2 electrode possesses superior electrocatalytic activity in the Is‘r electrolyte．Finally，the DSSC based on the hollow spherical NiS／NiS2 CE achieves a sati