结构确定的abc三元共聚物的合成和表征-高分子化学与物理专业论文.docxVIP

中国科学技术大学硕士毕业论文应，与己二醇酯化反应，这两步反应赋予端基两种不同功能反应基团，羟基和活 中国科学技术大学硕士毕业论文 应，与己二醇酯化反应，这两步反应赋予端基两种不同功能反应基团，羟基和活 性溴．ATRP条件下活性溴引发苯乙烯聚合，然后进行去卤反应，羟基和丙烯酰 氯进行酯化反应便得到大分子单体．研究了这种大分子单体的均聚和与丙烯酸 叔丁酯的共聚的反应行为． 关键词：原子转移聚合：确定结构的大分子：两亲性嵌段共聚物 中国科学技术大学硕士毕业论文Abstract 中国科学技术大学硕士毕业论文 Abstract Recently,synthesis and properties of block copolymers with complex well—defined molecular architecture，such as star,Ⅱ一／H—shaped，and hyperbranched copolymers， have attracted much attention．A strong motivation is that，to find out the relation between the structure and propeay ofpolymers is an ultimate goal ofpolymer science． However,due to synthetic difficulty,it is still a challenge to synthesize well-defined polymers with designed structure for polymer chemists．In the past decade，the advance in living／controllable radical polymerization，namely,atom transfer radical polymerization(ATRP)，nitroxide—mediated polymerization(NMP)and reversible addition fragmentation Uansfer(RAFT)polymerization，provide a powerful toul for designing and synthesizing well-defined polymers． This contribution describes synthesis of three types of copolymers with well-defined molecular architectures． 1， An amphiphilic rod-coil ABC triblock copelymers with rigid oligo(para-phenyleneethynylene)(0PE)as the middle rod segment，poly(ethylene oxide)一block-oligo(para-phenyleneethynylene)一block-polystyrene饵EO—b—OPE·b-PS)， was designed and successfully synthesized．Fisrt，a macminitiator,PEO-b-OPE—Br Was achieved by stepwise coupling of iodo—terminated poly(ethylene oxide)and oligo(para-phenyleneethynylene) with amino end group， capping with 2-bromopropionyl bromide．Subsequently,triblock copolymer，PEO·b—OPE-b-PS was obtained by performing atom transfer radical polymerization(ATRP)of styrene from this macroinitiator．The resulting copolymers were characterized by nuclear magnetic resonance(NMR)and gel permeation chromatography(Gec)．The novel copolymers were affirmed to have well·defined structures and narrow molecular weight distributions． 2．The