聚硅氧烷改性聚氨酯显色基团的结构机理与表征-高校化学工程学报.PDF

21 1 No.1 Vol.21 2007 2 Journal of Chemical Engineering of Chinese Universities Feb. 2007 1003-9015(2007)01-0126-05 1 2 2 1 , , , (1. , 310012; . , 310027) (PEG)(TDI)(GY-23) N- (ZC-10) 5.87% 0.72 µm (GRK) FT-IR 1H-NMR GRK -C H (CH )-NH-COO- 6 3 3 (Si(CH ) -O-) -( ) -( ) 325.2 nm 3 2 n , lg = 0.425 ( )-ArNHCOO - n d p * TQ316.334 TQ323.8 A Characterization of Coloring Structure Unit of Polysiloxane Modified Polyurethane Latex 1 2 2 1 ZHU Chun- feng , LI Bo-geng , YAO Ming , SUN Xiao-ying (1. Department of Biological and Chemical Engineering ,Zhejiang University of Science Technology, Hangzhou 310012, China; 2. State Key Laboratory of Chemical Engineering, Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China) Abstract: Polysiloxane modified cationic water-bone polyurethane (GRK) latex was prepared by condensation polymerization of polyethylene glycol (Mn=1000), 2,4-tolyerne diisocyanate (TDI) and hydroxyl terminated organ-silicone. With 5.87 %(wt) N-methyldiethanolamine (ZC-10), the obtained latex is stable and has a brown color with the average particle size of 0.724 µm, and the coating formed from it is opaque and has li