微生物沉积碳酸钙修复水泥基材料表面缺陷-硅酸盐学报.PDF

第36 卷第4 期 李为民等：玄武岩纤维对混凝土的增强和增韧效应 · 457 · 第36 卷第4 期 硅 酸 盐 学 报 Vol. 36 ，No. 4 2 0 0 8 年 4 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY April ，2008 微生物沉积碳酸钙修复水泥基材料表面缺陷 王瑞兴，钱春香 (东南大学材料科学与工程学院，东南大学绿色建材技术研究所，南京 211189) 摘 要：用涂刷技术，以琼脂作为载体将菌株和营养物质固载于水泥石表面，创造菌株生长、酶化和碳酸钙沉积的微环境，7 d 后能在水泥石表面紧 密附着生成厚度100 μm 左右的碳酸钙膜，其表面吸水率可以降低到覆膜前的15%以下；同时将高浓缩菌株与砂基材拌合，并混合尿素和Ca2+ ，制备 成浆体，注入到水泥石人造裂缝中，通过定时滴加修复营养液的方法，逐渐在裂缝砂粒之间矿化沉积出碳酸钙，最终将砂粒紧密胶结在裂缝内，达到 裂缝修复的目的，28 d 抗压强度可恢复至84%，效果显著。通过涂抹工艺和注入工艺的实现，可在材料表面原位矿化沉积出方解石，增强了微生物修 复在实际工程中应用的可操作性。 关键词：碳酸盐矿化菌；碳酸钙；缺陷；修复；覆膜 中图分类号：TU526 文献标识码：A 文章编号：0454–5648(2008)04–0457–08 RESTORATION OF DEFECTS ON THE SURFACE OF CEMENT-BASED MATERIALS BY MICROBIOLOGICALLY PRECIPITATED CaCO3 WANG Ruixing，QIAN Chunxiang (College of Materials Science and Engineering, Research Institute of Green Construction Materials, Southeast University, Nanjing 211189, China) Abstract: A CaCO3 layer was produced by brushing immobilized bacteria and nutriments onto the cement paste surface after 7 d. The deposited layer was about 100 μm and bound with the surface tightly. A carrier was used to immobilize the bacteria with agar, which could provide a microenvironment for bacterial growth, urea digestion and CaCO3 deposition. The experimental results show that the capillary water absorption of the treated specimens is 85% lower than that of the untreated specimens. Furthermore, by injecting the paste, which consisted of highly condensed biomass, sand, urea and Ca2+, into artificial cracks of cement stones, and by adding nutri- ent solution, CaCO3 particles would gradually precipitate among the sand