形貌依赖的ZnO阴极射线发光性质研究.PDF

第35卷摇 第6期 发摇 光摇 学摇 报 Vol郾35 No郾6 2014年6月 CHINESEJOURNAL OF LUMINESCENCE June,2014 文章编号:1000鄄7032(2014)06鄄0672鄄06 形貌依赖的ZnO阴极射线发光性质研究 * 吕珊珊,楚学影 ,王记萍,方摇 芳,李金华,方摇 铉,魏志鹏,王晓华 (长春理工大学 理学院,吉林 长春摇 130022) 摘要:采用溶剂热法,通过调节水和乙醇混合液的比例制备了多种形貌的ZnO微米结构。 利用扫描电子显 微镜(SEM)对ZnO微米结构的形貌及尺寸进行了观察。 采用可以实现纳米级微观区域光谱采集的阴极射线 发光(CL)技术,对不同形貌的单个粒子的光谱进行精细表征,获得了位置依赖的ZnO阴极射线发光数据。 实 验结果表明:ZnO材料的发光性质与形貌有关,由于形貌差异导致其局部结晶质量、界面缺陷、表面电荷分布、 表面晶面等方面的差异,几种因素共同作用决定其最终的发光性质。 关摇 键摇 词:ZnO;阴极射线发光;形貌 中图分类号:O469摇 摇 摇 文献标识码:A摇 摇 摇 DOI:10.3788/ fgx0672 Investigation of Morphology Related Cathodoluminescence Properties of ZnO Microstructure * LYU Shan鄄shan,CHU Xue鄄ying ,WANGJi鄄ping, FANG Fang,LI Jin鄄hua,FANG Xuan,WEI Zhi鄄peng,WANG Xiao鄄hua ( School of Science,Changchun University of Science and Technology,Changchun 130022,China) *Corresponding Author,E鄄mail:chuxy608@163.com Abstract:ZnO microstructure was prepared by solvothermal method. The morphology varied only with the proportion of deionized water and ethanol in the solvent. The morphology and size of the ZnOmicrostructurewereobservedby scanning electronmicroscope (SEM). The spectraof theindi鄄 vidual particleswith different morphology have been carried based on a detailed characterization by cathodoluminescence (CL) technique which could achieve nanoscale region optical properties. The spatially dependent CL results of the synthesized ZnO microstructurewere obtained. It isfound that the luminescencepropertiesarerelatedtothe morphology of ZnOmaterials,becausethe morphology difference woul