NiCo2O4纳米片的电化学方法制备及其超级电容性能研究毕业.docxVIP

毕业论文 论文题目（中文）NiCo^Q殳纳米片的电化学方法制备及其超 级电容性能研究 论文题目（夕卜文）Electrochemical synthesis of NiCo^Q - nanosheets for supercapacitors NiCo2O4纳米片的电化学方法制备及其超 级电容性能研究 摘要 NiCo2O4是一种制备工艺简单的高性能超级电容器电极材料，将其生长在大 比表面积的导电基底上更能体现其优秀的电容性能。在本研究中，我们首先采用 电化学沉积的方法在三维多孔泡沫银基底上生长了 Ni-Co双氢氧化物，然后通过 退火处理得到了片状的NiCozCU纳米电极材料。我们利用扫描电子显微镜(SEM) 和X射线衍射(XRD)表征了 NiCo2CU纳米片的形貌特征。通过恒流充放电(GCD) 和循环伏安法(CV)对NiCo2O4电极材料的电化学性能进行了表征。测试结果表 明：当沉积量达到0.24 mg时(窗口电压-1 V沉积时间5 min)，获得的样品 (NiCo2O4-5),具有最优的电化学性能，其在充放电电流密度为30 mA cm2时， 具有最高比电容值333.3 FgL这表明NiCo2O4纳米片是一种前景可观的超级电 容器电极活性物质。 关键词：NiCo2O4纳米片；泡沫镰；电化学沉积；超级电容器 ELECTROCHEMICAL SYNTHESIS OF NiCo2O4NANAOSHEETS FOR SUPERCAPACITORS Abstract NiCo2()4 is a high-performance electrode material for electrochemical supercapacitors, which can be prepared by facile methods. It is desirable to grow NiCo2°4 on conductive substrate with high surface area material to reflect its excellent capacitive performance. In this study, we firstly prepared Ni-Co hydroxide nanosheets on nickel foam substrates by a facile electrochemical synthesis, and then the hydroxides turned into NiCo?C)4 after an annealing process. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to characterize the surface morphology of the NiCo2O4 nanosheets- Galvanostatic charge-discharge (GCD) and cyclic voltammetry (CV) measurements were used to evaluate their capacitive performance. The results show that the sample with mass loading of 0.24 mg (-IV，5 min) (NiCo2°4-5) can demonstrate the best electrochemical performance? At the current density of 30 mA cm the highest specific capacitance of the NiCo2°4-5 is 333.3 F g which indicates that NiC()2°4 is a promising active material for supercapacitors? Key words： NiCo2°4 nanosheets; Nickel foam; Electrochemical deposition; Supercapacitor TOC \o 1-5 \h \z HYPERLINK \l bookmark4 \o Current Document 摘要 II HYPERLINK \l bookmark8 \o Current Document Abstract ill HYPERLINK \l bookmark10 \o Current Document 第一章前言 1 HYPERLINK \l bookmark12 \o Current Docume