球形高分子刷作为包装纸防潮涂料初探-包装工程.PDF

包 装 工 程 第 38 卷 第 23 期 ·12 · PACKAGING ENGINEERING 2017 年 12 月 球形高分子刷作为包装纸防潮涂料初探 苏娜 （上海出版印刷高等专科学校，上海 200093 ） 摘要： 目的 以二氧化硅为核、聚甲基丙烯酸甲酯为刷制备球形高分子刷，考察其作为包装纸防潮涂料 主要成膜物质的性能。方法 采用“从表面接枝”技术，通过引发剂引发单体聚合生成甲基丙烯酸甲酯 球形刷，利用 FTIR 和 TEM 对球形高分子刷的结构及形态进行表征，并考察其作为涂料成膜物质的应 用性能。结果 合成的球形高分子刷具有良好的耐水性能，且在固含量达到 40% 以上时仍具有较低的粘 度（64 mPa·s ）。结论 该球形高分子刷具有高固低粘包装纸防潮涂料的应用价值。 关键词：球形高分子刷；固含量；粘度；防潮涂料 中图分类号：TB484.1 文献标识码：A 文章编号： 1001-3563(2017)23-0012-04 Preliminary Approach on the Spherical Polymer Brushes as Moisture-proof Coating of Packaging Paper SU Na (Shanghai Publishing and Printing College, Shanghai 200093, China) ABSTRACT: The work aims to prepare the spherical polymer brushes with silicon dioxide as the core and polymethyl methacrylate as the brush, so as to investigate the properties of spherical polymer brushes when taken as the mois- ture-proof coatings main film-forming material of the packaging paper. With the technology of grafting from the sur- face, the methyl methacrylate spherical brush was generated by initiating the monomer polymerization through the in- itiator. The structure and morphology of spherical polymer brush were characterized by FTIR and TEM, and the applica- tion performance of the spherical polymer brushes treated as the coating film-forming material was investigated. The synthetic spherical polymer brush had good water resistance and still had a low viscosity (64 mPa ·s) at a solid content of over 40%. The spherical polymer brush has the application value in moisture-proof coating of p