固相法合成LiFePO4正极材料的性能研究-材料学专业论文.docxVIP

固相法合成 固相法合成 LiFePO4 正极材料的性能研究 STUDY ON PERFORMANCE OF LiFePO4 CATHODE MATERIAL SYNTHESIZED BY SOLID-STATE REACTION ABSTRACT LiFePO4/C and LiFePO4-xFx/C samples were synthesized by carbothermal reduction method in this paper. The microstructures and morphologies of these composites were characterized by XRD, SEM, TEM, Raman and FTIR observations. The electrochemical performances were evaluated by galvanostatic charge-discharge test system. The effects of consumption amount of lithium salt, new organic carbon source and F-doping on the physical and electrochemical systematically investigated. The experimental results found that LiFePO4/C with 8% excess of lithium salts, exhibited similar particle size and optimal electrochemical performance, whose initial discharge capacities could reach 156.6 and 143.5mAh/g at 0.2C and 1C rates, respectively, with a cycling capacity retention rate of 99.8% after 100 cycles at 2C rate. LiFePO4/C samples were prepared with glucose, polyvinyl alcohol (PVA), polyethylene glycol (PEG) as carbon sources, respectively. The results showed that the graphitization degree of coated-carbon had little effect on the conductivities of LiFePO4/C samples. Among which LiFePO4/C with glucose as carbon source had a highest electronic conductivity of 5.70×10-2S/cm, while the sample with PEG as carbon source had a lowest electronic conductivity of 5.59×10-2S/cm. But the with PEG as carbon source showed the optimal electrochemical performance, whose initial discharge capacity could reach 155.9mAh/g at 0.2C rate, with a cycling capacity retention rate of 103% after 50 cycles at 3C rate. The orthogonal test L9(33) was designed for the LiFePO4/C sample with PEG as carbon source and 8% excess of lithium salts to study the effects of calcination temperature, time, and C doping amount on the properties of samples using the initial discharge capacity at 0.2C rate ii 河北工业大学硕士学位论文 河北工业大学硕士学位论文 as an indicator. The obtained optimal prepara