含脂肪胺聚氧乙烯醚结构单元的PUS的制备及性能-化学工程与技术专业论文.docxVIP

烷基、主链嵌入季铵阳离子和大量聚氧乙烯结构的较高分子量的阳．非离子 烷基、主链嵌入季铵阳离子和大量聚氧乙烯结构的较高分子量的阳．非离子 型PUS(简称为cPU)。实验研究表明，随着扩链剂PEG分子量的增大， 合成的CPU的黏度逐渐变大，表面张力由38．12mN／m增加到45．41mN／m， 临晃胶束浓度由53．10mg／L增大到63．53mg／L；且当用PEG．200进行扩链时， 合成的CPU表面性能最佳，溶液的临界胶束浓度为53．]0mg／L，水溶液的 表面张力最低可达38．12mN／m。 在十二胺聚氧乙烯醚(10)与IPDI进行预聚并用二羟甲基丙酸(DMPA) 扩链的反应体系中，固定反应体系总R值为1．1，控制PAE与DMPA的物 质的量之比分别为2：1、1：1(2：2)、2：3、2：4，可以制备系列侧链含长链烷 基和羧基、主链嵌入季铵阳离子和聚氧乙烯结构的阳．非．阴多离子型的PUS (简称为APU)。实验研究表明，当n(PAE)：n(DMPA)=1：1时，合成 的APU的表面性能优异，溶液的临界胶束浓度为32．26mg／L，水溶液的表 面张力最低可达40．42mN／m；且其等电区为3．5,---5．5，具有较窄的等电区分 布，可在较宽的pH范围的水性体系中具有良好的表面活性。 关键词：脂肪胺聚氧乙烯醚，异佛尔酮二异氰酸酯，二羟甲基丙酸，聚氨酯 表面活性剂 万方数据 PREPAR PREPAR ATIoN AND PROPERTIES oF PUS EMBEDDED THE STRUCTURAL UNITS oF F2▲TTY AMINE PoLYoXYETHYLENE ETHER ABSTRACT Polyurethane surfactant(PUS)was designed and synthesized by introducing hydrophilic ionic or nonionic segment in the traditional main chain of polyurethane，which made polyurethane become new functional polymer materials with arnphiphilic s加cture．Meanwhile，it also became a hot spot in the field of functional polyurethane materials．However,the studies mainly on the anionic and nonionic materials，and few on cationic materials．Furthermore，the researches on cationic-·nonionic and cationic··nonionic-·anion type of PUS were more less．The synthesis and performance research have potential applications due to the special stmcnlre of many ionic type of PUS． A series of PAE-IPDI prepolymers with different structure were synthesized in the medium of acetone by changing the isocyanate index(R value)，and it’S raw materials containing polyoxyethylene alkyl amine(PAE) and 3-isocyanatomethyl-3，5，5-trimethylcyclohexyl isocyanate(IPDI)．Based on the synthesis methods and conditions，the effect of the carbon number of aⅡ呼l side chain and ahyl phenol polyoxyethylene on the emulsion particle size，surface tension and emulsifying power were researched．The e舵ct of additional electrolyte on surface tension were also showed．The properties of emulsion were measured by infrared spectroscopy(FT