固硫灰特性及其复合胶凝材料的性能研究-材料学专业论文.docxVIP

摘要复合胶凝材料的变形性能。 摘要 复合胶凝材料的变形性能。 固硫灰复合胶凝材料的膨胀率大于纯硅酸盐水泥膨胀率，随掺量增大，膨胀 率增大，且在28d时均基本达到膨胀稳定期。固硫灰含硫量≥10％，其掺量由30％ 增至45％时，膨胀率增加量急剧增多。当其含硫量为13％，掺量达到45％时， 复合胶凝材料的膨胀率超出了安全范围。固硫灰含硫越高，复合胶凝材料干燥收 缩后残余伸长率愈大，膨胀可转化为预加应力进行较长时间的收缩补偿。 4、主要选择抗硫酸盐侵蚀和抗冻性两个指标来评价掺加固硫灰在耐久性方 面的表现。 复合胶凝材料随固硫灰掺量的增加其抗硫酸盐侵蚀性降低；含硫5％固硫灰 耐蚀性安全掺量约为40％；含硫7％固硫灰耐蚀性安全掺量约为35％；含硫≥10％ 固硫灰耐蚀性安全掺量约为3096；同时，各品质的固硫灰均能改善复合胶凝材料 的抗冻性，且随含硫量的增加其改善效果也逐渐增强；含硫量13％的固硫灰，掺 量约为30％时，改善效果最为明显。 5、在上述结果的基础上，对固硫灰进行应用安全阈值分析。 利用52．5强度等级硅酸盐水泥熟料，掺加固硫狄生产生态型水泥时，掺含 硫量S5％固硫灰，其安全掺量宜型O％，为42．5强度等级水泥；含硫量7％固硫灰， 其安全掺量宜S35％，且掺量31％时为42．5强度等级水泥，掺量3l％～35％为 32．5强度等级水泥；含硫量210％固硫灰的安全掺量略大于30％，为42．5强度等 级水泥。与普通水泥相比，配制的生态型水泥具有长期强度大、补偿收缩、良好 的抗冻性、有效的抗硫酸盐侵蚀性等优越性。， 关键词：固硫灰胶凝材料强度耐久性安全阈值 AbstractAbstract Abstract Abstract In China,compreshensive resourse utilizationg of industrial waste is one of the most important measures for achieve the‘‘green’’economy and the sustainable development of industry．Sulfur ash is one of the main products by the thermal power plants after they have controled the emiss i on of sulful dioxide．containing some bumt clay minerals，and similar with ash at chemical composition，suitable for the building materials’raw material．But there are some different problms，such as the great quality difference，containing minerals and residual lime which will lead to the poor stability in the complex binding materials．In current the utilization of sulfur ash at a low level， which Was treatmented by heap or landfill．At present the application of sulfur ash is mainly refer the uti lization of fly ash，and its application on the potential impact of buliding materials has not been fully demonstrated．The main purpose of this study is using sulfur ash largely in industry．on the one hand that will be help to reducing the cost of desulfurization after improving their industial added value，then promoting the measures for desulphurization in thermal power intustry in our country,at the other hand，that could be effectively reduce environmental pollution in cement and concrete ind