加热移除废弃聚氨酯硬泡中CFC-11的研究.PDF

中国环境科学 2009,29(4) ：397~401 China Environmental Science 加热移除废弃聚氨酯硬泡中 CFC- 11 的研究 1,2 2* 2 1 2 杨 勇 ,刘景洋 ,郭玉文 ,杨 敏 ,乔 琦 (1.西南交通大学环境科学与工程学院, 四川 成都 6100312 ； 中国环境科学研究院,北京 100012) 摘要：研究了聚氨酯硬泡在不同温度加热过程中的质量损失、生成的气体成分及硬泡结构变化,并对加热聚氨酯硬泡时所释放的发泡剂 CFC-11(CCl F)进行了测定.结果表明,在 80~160℃加热聚氨酯硬泡时,CFC-11 的释放速率随温度的增加而增加.将破碎后的硬泡颗粒在 3 160℃下加热,既保证硬泡颗粒不发生热解反应,又使包裹和吸附于硬泡中的 CFC-11 移除速率最快.在 160℃下加热过 4mm 筛硬泡颗粒 1,2,4h 后，可分别移除的 CFC-11 占硬泡颗粒中总量的84.5%、95.5%和 96.6%,残余 CFC-11 则需足够长时间才可移除,而加热释放气体中 CFC-11 占82%~85%. 关键词：废弃聚氨酯硬泡；加热；移除；发泡剂 CFC-11 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2009)04-0397-05 Studies on removing CFC-11 by heating from discarded rigid polyurethane foams. YANG Yong1,2,LIU Jing-yang2*, 2 1 2 GUO Yu-wen ,YANG Min , QIAO Qi (1.School of Environmental Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China ；2.Chinese Research Academy of Environmental Sciences, Beijing 100012, China). China Environmental Science, 2009,29(4)：397~401 Abstract ：The mass loss, emitted gas composition and structure change of rigid polyurethane foam (PUR foam) at different temperature were investigated, and the amount of released blowing agent, CFC-11 (CCl3F) was determined when PUR foam was heated. The release rate of CFC-11 increased with the rise of temperature when the temperature was in range of 80~160 ℃. At 160℃, particles of PUR foam were not decomposed and the CFC-11 that was adsorbing or wrapping in PUR foam was removed at the highest speed. Foam particles which were through 4mm sieve were heated to 160℃ for 1h, 2h and 4h, respetively, then the corresponding 84.5%, 95.5% and 96.6% amount of CFC-11 in the foam particles was removed, respectively.