钴纳米颗粒及钴镍合金亚微米颗粒结构控制合成与表征-材料科学与工程、材料物理与化学专业论文.docxVIP

兰州人学硕上学位论文Abstract 兰州人学硕上学位论文 Abstract The study on how to adjust and control the properties of materials by controlling the morphology,size and crystal structure of nano—particles have attracted much attention in the research of nano．materials，for when the size of the particles decreases to nano-scale，the morphology,size and crystal structure of nano—particles will affect the performance of materials．In this study,we used a solvent-thermal polyol process to control the crystal structure of Co nano-particles，and successfully prepared single—phase HCP or FCC and HCP and FCC phase-mixed Co nanoplatelets．We also prepared the FCC Co—Ni alloy sub-micro particles over the whole composition range and preliminary studied the mechanisms of crystal structure transformation in the preparation．The structure and the magnetic properties of Co nanoplatelets and Co-Ni alloy sub-micro particles were characterized． (1)Single—phase HCP or FCC and HCP and FCC phase-mixed Co nanoplatelets were synthesized via a simple solvent—thermal process，in which ethylene glycol was used as both solvent and reducing agent，and cetyltrimethylammonium bromide(CTAB)as control agent． It was found that the CTAB concentration in the reaction solution had a grate influence on the final structure of the products．All the samples synthesized with the CTAB concentrations between 0 and 50 mM for the reaction time of 5 h were the pure FCC phase．For the reaction time of 15 h，with the CTAB concentration in the reaction solution increasing from 0 to 5 mM， the FCC and HCP Co transformed to the thermodynamically stable HCP phase after the redox reaction．For the reaction time of 15 h and the C11AB concentrations in the reaction solution between 5 to 9 mM，the single—phase HCP Co nanoplatelets were obtained．But this phase transformation did not occur if the CTAB concentration was above 10 mM．Magnetic measurements revealed that both of HCP and FCC Co nanoplatelets were ferromagnetic．The saturation magnetizations(肘s)of the