含氟苯甲酰基硫脲衍生物的合成、阴离子识别性能及植物生长调节活性研究-无机化学专业论文.docxVIP

硕士学位论文 硕士学位论文 中文摘要 析化学提供了一种可鉴的方法。 3．概述了植物生长调节剂、酰基硫脲类衍生物在农药方面应用以及芳香族含氟 化合物的特性、在生物活性方面的应用。 4．利用简便方法合成并表征了3种2，2’一二含氟苯甲酰基硫脲基乙二醇二苯醚。 采用平皿培养法，比较了在彳i同溶液浓度下其与Ⅳ-含氟苯甲酰基w一芳基硫脲对 油菜籽和小麦种子生长调节作用。结果表明，该3种二硫脲衍生物的低浓度溶液 对双子叶植物油菜和单子叶植物小麦促进生长作用优于Ⅳ-含氟苯甲酰基w一芳 基硫脲和吲哚乙酸。结果符合活性子相加原理。特别是含三氟甲基的化合物1c 有望开发为新型植物生长调节剂。 关键词：含氟苯甲酰基硫脲；合成：阴离子识别；植物生长调节活性 硕士学位论文 硕士学位论文 巾文摘要 Abstract Acylthiourea derivatives have been patented as antidiabetic，antiarthritic， antineoplastic，and anticoagulant and prostate disorder．Herbicidal，fungicidal， bactericidal，insecticidal and plant growth regulator activities have also been reported． In addition．N-substitutedⅣI—carbonyl thiourea compounds have attracted considerable attention in recent years due to their anionic recognition properties and coordination abitity with transition metal ions．Owing tO their strong coordination ability,many aeylthioureas are extensively utilized as the sequestering agent for copper sulfides and precious metals．Moreover fluorinated aromatiC compounds play an important role as intermediates or materials in preparation pharmaceuticals， pesticides and dyes last decade．In this thesis，we have synthesized some novel N-flurobenzoyl-N一phenylthiourea derivatives and studied on their anion recognition properties and activities of these compounds aS plant growth regulators．The major COntents are as follows： 1．Researches in the development of anion recognition were briefly reviewed．The content of this chapter includes：(i)molecular of recognition，(ii)the structural characters of anions，(iii)noncovalent interactions existed in anion coordination，(iv)the development ofanion recognition researchers of urea and thiourea derivative receptors，(V)the development of anion recognition properties of ttfiourea in water-containing media． 2．A novel series of N-flurobenzoyl-N一phenylthiourea have been prepared by simple steps in good yields and characterized，The binding properties of some of the receptors with anions such as F‘，C1‘Br-，CH3COO+，HS04’and N03’were examin