硅丙弹性体的合成与表征-化学工程专业论文.docx

浙江大学硕士学位论文Abstract 浙江大学硕士学位论文 Abstract Polysiloxane seed emulsion was prepared by anionic emulsion polymerization of D4 and VD4．Silicon-acrylic copolymer was synthesized by seed emulsion polymerization．Silicon-acrylic elastomer which has excellent properties was synthesized by curing． The effects of catalyst,emulsifier and temperature on the dynamics of polymerization was studied．The results showed，when the temperature is 75～85C， the content of DBSA is 3％，the content of SDBS is 1％，stable polysiloxane seed emulsioncanbesynthesized． 111e effects of feeding method．temperature,emulsifier,initiator,the content of seed emulsion and the mole ratio of D4／VI)4 on the dynamics and stabilization of polymerization were studied．Silicon-acrylic copolymer was characterized by I DSC and TGA．The study showed，silicon-acrylic copolymer which has excellent properties Can be synthesized at the situation that the temperature is 70～850，the content of emulsifier is 1．5-2％,the content of initiator is 0．2~o．3％．the content of polysiloxane is 10％and the mole ratio of D4／VD4 is 20／1．The results showed that polysiloxane had been copolymerized with acrylate monomers by IR and DSC．TGA indicates,the heat resistance is improved by the introduction ofsilaxone． Silicon-acrylic copolymer can be cured by fatty amine or epoxy resin．The properties of silicon-acrylic elastomer cured by composite curing agent E6101／HA(I／1)was excollant．The results showed，silicon-acrylic elastomer witll excellent properties Can be synthesized at the situation that the curing agent is composite curing agent E6101／HA(1／1)and its content is 3(mass ratio)，the filling agent is N330／N55(2／1)and its content is 50(mass ratio),the content ofpolysiloxane islO％． Key words：seed emulsion polymerization；silicon-acrylic copolymer；curing； silicon-acrylic elastomer；characterized；composite curing agent；filling agent Ⅱ 浙江大学硕士学位论文第一章前言 浙江大学硕士学位论文 第一章前言 丙烯酸酯橡胶(简称AcM)其主链结构为饱和结构，又具有极性的酯侧基， 因而具有优良的耐热、耐油、耐氧化、耐天候等特性，是一种高温耐油橡胶。随 着我国汽车工业、电力工业的快速发展，ACM的