几种矿物的低温液相合成 生长机理及其性能研究-材料物理与化学专业论文.docxVIP

中科科学技术大学博士学位论文AbstractAbstract 中科科学技术大学博士学位论文Abstract Abstract In this dissertation，versatile methods were used to control size，shape， polymorph and hierarchy of CaC03，CeOHC03 and rutile-Ti02 minerals．For biomineralization study,one double hydrophilic block copolymer with a rigid functional group(PEG-b—hexacyclen macrocycle)directed round disc-like calcite crystals with layered structure，which is similar to nacre of Haliotrufescens． Amorphous calcium carbonate(Ace)nanoparticles were synthesized by a gas-diffusion process，which was used as precursor for transformation and crystallization of CaC03 polymorph．It is found that a fine adjustment of thermodynamic-kinetic equilibrium has a strong effect on the formation of metastable kinetic phase．M@Ti02(M=Ag，Au，Pt)naonocomposites can be successfully synthesized by a photoreduction process．Ag@ITi02 and Au@lTi02 exhibited excellent antibacterial properties against E coli．， when the dosage of metal concentration reached to 1 0p．g／m1．When these nanocomposites fulfilled a photooxidation polymerization process，metal@ITi02一conductive poly(phenylenediamine)hybrid materials formed．The main results can be summarized as following： 1．PEG—b—hexacyclen macrocycle was used as crystal growth modifier, controlling formation of layered structure CaC03 with similar structure of nacre． Besides the epitaxial match between pattem of functional group of the copolymer and special crystal face of calcite，particle stabilization，crystallization time，time for polymer rearrangement，and surface·ion density play roles on the formation of this layered structure． 2．In a gas—diffusion process，well—dispersed amorphous calcium carbonate nanoparticles were synthesized in ethan01．The nanoparticles can be stable in ethanol for several months，and its size distribution doesn’t change even after condensation or ultracentrifugation．Crystallization behaviour of the amorphous calcium carbonate were investigated，a lot of structures，such as calcite rhomb，curved CaC03 n