加压光气法制MDI技术开发-有机化学专业论文.docxVIP

IlI自、人中顶十学位论文ABSTRACT IlI自、人中顶十学位论文 ABSTRACT MDI is one of the most important material in polyurethane industry，it is producted by phosgenation of polyamine which is contracted by aniline and formaldehyde，and then the complexity is separated to made MDI．MDI includes pure MDI and polymerid MDI．The pure MDI has three kinds of isomer：4，4-MDI，2,2’MDI， 2,4’MDI．The 4,4’MDI is used in the most abroad fieldes ofthese kinds．Pure MDI is mostly used in the‘CASE”fieldes C-coatings,A-adhesives，S-sealants,E-elastomers．)in polyurethane industry．Polymelric MDI is important material to make polyurethane horniness and semi．homi—ness foam． With the fast development of the polymctlmne indistory,the reguirement of MDl which is important material is increasing．The technician of YanTaiWanHua manufactory had researched the reaction technology in super pressure．We increased pressure solely in the cole reaction pmcessme in order to reduce the phosgenation circle ratio and improve MDI’S chroma of the phosgenatiou liquor,at last we advanced produce ability and decrease the energy． This research based on small suit of uninterrupted phosgenation equipment which simulates the production equipment．We can say it is a minisize manufactory．We made detailed research of the whole phosgenation courses with the mini·manufactory． Because of the sanle technic，opration control as the real manufactory,the research is important to make over the real operation． The research report is across the abroad．It involves reaction technics,reaction principle，infection of the material，technic parameter,judge of the reaction and SO on．Some research technique and analysis means are reliable of the report．We believe that the cold reaction is the emphases of the research and estimate it with the composition analyse． Key words：polyurethane phosgene MDI material parameter 4 山尔人学倾十学待论文第一节绪论 山尔人学倾十学待论文 第一节绪论 1．1本技术开发的意义 聚氨酯是聚氨基甲酸酯的简称，是指在高分子主链上含有重复的-NCO基团的 高分子化合物的通称，它是60年代后期发展起来的高分子材料，它既有橡胶的弹 性，又有塑料的强度和优异的加工性能，具有橡胶、塑料的双重优点，尤