缓凝剂对建筑石膏性能的影响和作用机理研究-材料学专业论文.docxVIP

英文摘要ABSTRACT 英文摘要 ABSTRACT Setting time ofgypsum plaster is very short，usually only 6-30 min，and operation time is only 5～10 min,which cannot sarisfy the practical plastering and construction of gypsum-based material．Selection of suitable retarding agent and its addition is particularly important for controlling the setting time of gypsum—based material in a certain rang，meeting the requirement of construction process．Though the retarder is widely used，the influence factor,the intrinsic reason that induces the strength drop and retarding mechanism are still studied superficially． In this thesis，the seRing time of various retarders had been tested，in which three retarders with good retarding action，citric acid，sodium tripolyphosphate，bone glue are respectively chosen from three types of retarders，hydroxyl carboxylic acid type， phosphate type and protein type，and the strength and setting time of gypsum added with them are determined．Effect of some factors，such as pH value，fineness of hemihydrate，type of gypsum on the retarding action of the retarders is also studied． Furthermore，By testing the supersaturation of liquid phase，hydration rate，hydration temperature as hydration of gypsum with the retarders，the effect of retarders on the hydration process is found out．The Scanning Electron Micrographs and the data of pore structure of gypsum and gypsum with the retarders also make US known the influence of retarders on the crystal morphology and pore structure，from which transformation of microstructure induced by retarders and the reason of which makes the strength drop are analyzed．Combined with the XPS spectrum，the mechanism of action with the retarders are finally proposed． Results of experiment show that the reason of strength decreasing of gypsom added with retarders is that the retarders reduce the supersaturation of liquid phase，and makes the crystal grain largen，and pore is followed to worsen,which lead to the strength drop to a large degree． Through the analyzing