分子蒸馏和同时蒸馏萃取法分析树苔浸膏的化学成分-食品科学.PDF

212 2012, Vol. 33, No. 10 食品科学 ※分析检测 朱怀远，庄亚东 * ，张 映，熊晓敏，万 敏，曹 毅，刘献军 (江苏中烟工业有限责任公司技术研发中心，江苏 南京 210019) 采用分子蒸馏法和同时蒸馏萃取法与气相色谱 - 质谱仪联用对树苔浸膏的化学成分进行分析。结果表明： 采用同时蒸馏萃取法共鉴定出 85 种化学成分，分子蒸馏法鉴定出 61 种成分，两种不同前处理方式所得萜类物质差 异较大，同时蒸馏萃取法所得萜类成分种类多于分子蒸馏法，但两种不同方式提取的主要成分相同，均鉴定出苔 黑酚单甲醚、分歧扁枝衣素单甲醚、扁枝衣酸乙酯、柔扁枝衣酸甲酯、 β- 苔黑酚羧酸甲酯、赤星衣酸乙酯、 苔黑酚羧酸乙酯、柔扁枝衣酸乙酯、棕榈酸乙酯、油酸乙酯、亚麻酸乙酯和亚油酸乙酯等成分，而且所占比例 较大(相对含量 76% 以上) ，为构成树苔浸膏典型苔清香的关键成分，同时，这些成分在分子蒸馏的重组分中得到 较好的富集。 树苔浸膏；分子蒸馏；同时蒸馏萃取；化学成分 Analysis of Chemical Constituents in Treemoss Concrete by Molecular Distillation and Simultaneous Distillation Extraction ZHU Huai-yuan ，ZHUANG Ya-dong* ，ZHANG Ying ，XIONG Xiao-min ，WAN Min ，CAO Yi ，LIU Xian-jun (Technology and Research Center of China Tobacco Jiangsu Industrial Co. Ltd., Nanjing 210019, China) Abstract ：Treemoss concrete was extracted with molecular distillation (MD) and simultaneous distillation extraction (SDE), and the extracts were analyzed by GC/MS. About 85 and 61 chemical components were extracted by SDE method and molecular distillation method, respectively. The terpenoid by two methods were significantly different. The variety of terpenoid by SDE was more than MD, whereas the major chemical components extracted by the two methods were the same. Among these chemical components, some had the higher concentration (above 76%) and they were identified as 3-methoxy-5-methylphenol, divarinol monomethyl ether, ethyl everninate, methyl divaricatinate, benzoic acid,2,4-dihydroxy-3,6-dimethyl-, methyl ester, ethyl hematommate, ethyl 2,4-dihydroxy-6-methylbenzoate, ethyl divaricatinate, ethyl palmitate, ethyl oleate, linolenic acid ethyl ester, linoleic acid ethyl ester and so