氨法脱硫烟气中气溶胶凝结脱除动力学-中国电机工程学报.PDF

第 31 卷 第 29 期 中 国 电 机 工 程 学 报 Vol.31 No.29 Oct.15, 2011 2011 年 10 月 15 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 41 文章编号：0258-8013 (2011) 29-0041-07 中图分类号：X 511 文献标志码：A 学科分类号：470.10 氨法脱硫烟气中气溶胶凝结脱除动力学 颜金培，杨林军，沈湘林 ( 东南大学能源与环境学院，江苏省 南京市 210096) Dynamics of Aerosol Condensational Removal in Ammonia Desulfurization Process YAN Jinpei, YANG Linjun, SHEN Xianglin (School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu Provience, China) ABSTRACT: A numerical model for the simulation of the 同条件下，细颗粒初始数浓度越高，完成凝结长大的时间越 aerosol condensational removal dynamics after ammonia 短，液滴的最终粒径也越小；细颗粒脱除效率随停留时间增 desulfurization was proposed to predict the growth property of 大迅速提高，在 50~100 ms 内达到稳定，与理论计算值比， fine particles and removal efficiency. The simulation model 实验停留时间滞后，约在 1.5s 后脱除效率趋于稳定；脱硫 was applicable for the aerosols discharge property of ammonia 后细颗粒凝结长大脱除效率与细颗粒物化性质有关，水洗涤 desulfurization. The results show that fine particles growth into 时，当过饱和度高于 1.4，细颗粒的脱除效率才随过饱和度 droplets is very fast in a supersaturation vapor condition. 的增大而迅速提高；氨法脱硫后，细颗粒可在较低的过饱和 Droplets complete growth time decrease and the final 条件下凝结长大，因而脱除效率随过饱和度增大而提高。 diameters of droplets are smaller at a higher initial particles 关键词：氨法脱硫；气溶胶；凝结；脱除 number concentration. The removal efficiency of fine particles increases rapidly with the residence time, and achieves stability 0 引言 after 50~100 ms. Compared with the simulated values, 细颗粒和 SO2 是我国大气环境中的主要污染 experimental residence time appeares delate, which tend to 物，给环境和人类健康造成严重危害[1-2] 。煤燃烧是 stabilize at 1.5 s. Fine particles removal efficiency improved by