环氧型耐热胶粘剂合成研究高分子化学与物理专业论文.docxVIP

中北大学学位论文 中北大学学位论文 Synthesis of heat-resistant epoxy adhesive Abstract Through modifying epoxy resin by chemical method , the purpose of this subject was to improve its heat aging resistance performance and enable them to work in high-temperature environment for long time. This thesis is mainly divided into two parts: the first part contains synthesis of epoxy pre-polymer modified by d part includes synthesis of epoxy pre-polymer modified by amino silicone oil and characterization of its bonding system; the second part includes synthesis of epoxy pre-polymer modified by silicone resin and characterization of its bonding system. Various binders have been obtained from silicone resin, amino silicone oil with the help of the curing agent polyamide resin and dicyandiamide. By the orthogonal experiment, the influencing factors of the properties of the binders have been systematically studied and the optimum process conditions have been confirmed. As the experiments showed that the synthesized epoxy resin modified by silicone resin at 58℃, for 6h had better performance. In addition, with dicyandiamide in the curing process, the epoxy resin cured at 158℃, for 1h the shear strength reaches 12.47MPa.The heat-resistant test has been carried out that the shear strength has been keeping 15MPa though worked at 141℃ for 60h. The epoxy resin modified by amino silicone oil has good performance at 90℃, with the proportion of epoxy resin: amino silicone oil: polyamide resin = 3:2:2. Key words: epoxy resin, binder, heat resistance, silicone resin, amino silicone oil I I 目 录 1 前言 1.1 环氧树脂的发展简介 1 1.2 环氧树脂胶粘剂的特性及发展 2 1.2.1 环氧树脂胶粘剂的特性 2 1.2.2 环氧树脂胶粘剂的分类 4 1.2.3 环氧树脂胶粘剂国内外发展动态 5 1.3 提高环氧树脂耐热性能的主要途径 7 1.4 有机硅改性环氧树脂的概述 8 1.4.1 有机硅改性环氧树脂的方法 8 1.4.2 有机硅改性环氧树脂的分类 12 1.4.3 有机硅改性环氧树脂的发展趋势 12 1.4.4 有机硅改性环氧树脂的应用前景 13 1.5 胶粘剂的粘结机理 14 1.6 本课题的研究目的与意义 15 1.7 本课题的研究内容 16 2 有机硅树脂改性环氧树脂耐热性研究 2.1 PVB 溶液的合成 17 2.1.1 合成原理 17 2.1.2 合成实验流程 17 2.1.3 实验所用药品及仪器 18 2.1.4 实验结果与讨论 19 2.2 有机硅改性环氧树脂