脉冲激光刻蚀聚合物及其光致发光性能研究-高分子化学与物理·高分子光电材料专业毕业论文.docxVIP

黑龙江大学硕士学位论文Abstract 黑龙江大学硕士学位论文 Abstract Researches on laser ablating polymer started in early 1980s，which has been widely used in many ways，For example，Using a UV laser photoablation method for the production of miniaturized liquid·handling systems on polymer substrate chips；People etching PI for micropattems by UV excimer laser,with this method，micropattems with micron．．scale line-width and sub．-micron depth have been successfully fabricated on PI； The surface of polymer(polyimide，polyethlene terephthalate)is modified by the irradiation from a focused excimer laser witll wavelength of 248nm with different energy densities．These changes ofstructure Call enhance the hydrophility ofthe surface． So far pulsed laser ablation has been widely applied to the surface modification of polymers，but the research about fluorescence performance of PE，PS ablated by pulsed laser has not been reported in the literature．It has attracted much attention from US，we decided do some research about it．In this thesis，a 1064nm pulsed laser Was used to ablate PE，PS using different current density．Compared to unmodified PE，PS on their fluorescence property． We used a 1064nm pulsed laser to ablate PE，PS using different current density． The ablated PE，PS gave off obvious blue light under UV lamp irradiation．We study on morphology of modified and unmodified PE，PS by scanning electron microscope， decide which one will be the right sample；The Fluorescence property of modified and unmodified PE，PS were studied by Fluorescence spectroscopy；The structure of modified and unmodified PE，PS were studied by IR spectroscopy,Raman spectroscopy and UV spectroscopy．We also used XPS to study the changes between modified and unmodified PS．The reSUIts showed that double bonds existed in the ablated PE，PS which which resulted in its obvious blue emission and the intensity of the laser had great influence Oil the physical properties and chemical structure ofthe PE surface． Key words：pulsed laser；surface ablation；