氯铝酸离子液体的制备及其对烷基化反应的催化作用-化工工艺专业毕业论文.docxVIP

墨誊鐾基王鎏竺墼型竺垒圣翌堡量些星璧塑堡些堡里AbstraCt 墨誊鐾基王鎏竺墼型竺垒圣翌堡量些星璧塑堡些堡里 AbstraCt Ionic liquid as a newen坍ronmentally friendly catalyst and solvents in the chemical industry will haVe broad prospects for application． The catalysis of chloroaIuminate ionic liquids in alkyjation process is studied in thjs article，ionic Iiquid’s synthesis，supported jonic liquid’s preparation and catalyst performance were included in the articIe． Ionic liquids are synthesized by difkrent cation， such as pyridine； 4一methyl-pyridine，imidazole and aluminum trichloride as anion．In order to improve the synthetical efHciency，the microwaVe assisted synthesis of[BMIm】cl have been studied．From the orthogonal experimentaI result，the pure products have been gained and e币ciency was improVed．The alkylation of benzene wjth alkene catalyzed is inVestigated．Raw material and products analyzed by gaschromatogram．Ionic liquids’s composition，weight，active，stability studied，some technicaI conditjons are tested．Through analysis the exper-ment datum，in this response the catalyst’s selectivity and activity are higher．In the aIkylation process of benzene，the ratio of benzene to olenn，the composition of catalysts，temperature and length of time have lmle ef怡ct on the conversion of olefin，but have efkct on the selectivity of 2一alkyI_benzene． Besides，immobilization of chloroaluminate ionic 1iquid on mesoporous sjlica by processes was car“ed out also．The catalyttc properties of the immobilized catalyst for benzene aIkylation with l_hexen were studjed and compared with the same type of common IL．The reaction selectiVity of the immobilized chloroaluminate ionic 1．quid haVe good selectiVity of 2．alkyl-benzene． Key Words：Ionic liquid；Supported Ionic liquid；alkylation；benzene；l—hexen II 兰州理工大学学位论文原创性声明 兰州理工大学 学位论文原创性声明 本人郑重声明：所呈交的论文是本人在导师的指导下独立进行研究所取 得的研究成果。除了文中特别加以标注引用的内容外，本论文不包含任何 其他个人或集体已经发表或撰写的成果作品。对本文的研究做出重要贡献 的个人和集体，均已在文中以明确方式标明。本人完全意识到本声明的法 律后果由本人承担。 作者签名：货芟辱一 日期：，，么年／月／日 ／ 学位论文版权使用授权书 本学位论文作者完全了解学校有关保留、使用学位论文的规定，同意学 校保留并向国家有关部门或机