黄酮类化学修饰电极性质研究及应用-应用化学专业毕业论文.docxVIP

化学修饰碳糊电极吸附溶出伏安法测定痕量锌ABSTRACT 化学修饰碳糊电极吸附溶出伏安法测定痕量锌 ABSTRACT Chemically Modmed Carbon PaSte Elec廿0de(cMCPE)is one of the、Ⅳidely used chemically modified elec订odes in electroanalytical chemis臼阱As me omer type of chemically modifled elec仃odes used in elec订oana州cal chefnjs吼CMCPE慨v撕ous adVantages，such lli曲selectiVity，sensitiVi吼prc-concen仃ation of analytes before me measllrements．The key poim of preparation of chemically modjfied elec订odes is to choose appropriate chemical modifier and the simplici哆ofthe prcpamtion． Quercetill and morin two kinds of navo工liod．They isomeric compounds． They caIl f0珊stable complexes砸tll many metalions，sO t11ey have been、^，idely used血 spectrophotome打ic aIlalysis，polarography，、rol诅mmctric aIlalysis．By mally expeTiments， two chemically modifled electrodes with quercetin and morin modifiers have been success削ly fabricated．The presem p印er desc订bed two ex仃即nely sensitive a11d selective s砸pping volt瑚eHc procedures for trace measuremem of zinc bascd electrodes mentioned above． T1le contents ofthjs thesis in the folIowing aspectS： 1．Quercetin chemically modified electmde was fabricated．The volt眦me仃y behavior of Zn(II)at the quercctin carbon paSte electrode was studied in detail．Under 也e condition of 0．5 m01‘L。1 acetatc bu行cr solution(pH4．7)，aIl elec廿0active complex of Zn(I【)witll quercetin was fonlled a工ld accllmulated on血e surf如e of tlle electrode at —O．2 V(vs．SCE)．Aner it was reduced at一1．O V for 40 s、vimout Stirrin臣the Volt猢ogram was then recorded by印plying a11 a110dizillg scaIl劬m一1．1 O V to 0．50 V at 200mV／S／rate，and an sensitive vol伯mmetric peak was obtained at加．85V Under optimized conditiolls，the 1．mear ranges was obtained in也e concentration ranges 1．oo x lO～～2．OO×10一m01．L一，ne detectionlimitwasfoundto be 5．00×10一m01．L～． 2．Morin chemically mod湎ed elec仃ode was fabricated．The voltammetry behavior ofZn(Ⅱ)at t}1e m鲥n carbon paste e】ec打ode was studied in detail．Under the condjtion of O．5 mol‘L．1 ace诅te bu脑solution(pH4．7)，an elec乜姐ct～e compleX of zn(