煤系高岭土表面包覆改性研究-工业催化专业毕业论文.docxVIP

中文摘要我国煤系高蛉土储量丰富，但是利用率低，资源浪费严重。究其原因是因为 中文摘要 我国煤系高蛉土储量丰富，但是利用率低，资源浪费严重。究其原因是因为 煤系高岭土中含有有机炭质，呈褐色致密坚硬的块状，缺乏可塑性、分散性，限 制了它的应用领域。因此，对煤系高岭土表面包覆改性，提高其利用价值具有现 实意义。 本研究通过加入分散剂得到分散良好的高岭土悬浮液，利用高温下尿素水解 产生的OH一与A12(S04)3反应生成灿(0H)3在高岭土粉体表面形成包覆，并测定反 应后高岭土的等电点(正P)，以此作为包覆效果好坏的判据。随后通过Ⅺm、FT —IR、TEM、SEM、EDS、BET等表征手段分析了包覆前后高岭土的各项性质并 进行对比，观察表面包覆后产生的变化。 分析结果表明；要想获得良好的包覆效果，必须严格控制反应条件。A13+浓 度过低或尿素浓度过大，体系成核较快，容易形成包覆后的高岭土与自身成核的 AI(OH)3的混合溶液；Ar+浓度过高大或尿素浓度过低，容易造成高岭土的局部 包覆；反应时间也不是越长越好，反应一段时间后高岭土的等电点不再发生变化。 试验结果表明：反应后在高岭土表面包覆了无定型的AI(OH)3。与包覆前的 高岭土相比，包覆后的高蛉土表面显得比较平滑，层状结构变得模糊，比表面积 减小；粉体等电点增大，显示出与AI(OH)3粉体类似的带电性质，分散稳定性得 到改善，达到了较好的包覆效果。 关键词：煤系高蛉士 尿素 表面包覆 等电点(mP) Coal-based Coal-based kaolin mineral SOUICe of China has all abundant reserves，but its utilization ratio is very low,which causes resources waste．This is because the coal-based kaolin mineral contains organic carbon,which results in lacking of plasticity and dispersibility and is very harmful to its applications．It has realistic meanings to improve its application p确加∞ncc by coating modification of coal．based kaolin mineral． In this paper,kaolin particle，A12(S04b and urea wele dispersed in deionized water by dispersants and ultrasound．1[11e suspension Was vigorously stirred and heated in 70C for some time followed by rapid cooling．1he powder Was washed wi也deionized water and ethanol several times．and then dried at 100℃．n伦 properties of coated kaolin is characterized and contrasted to uncoated kaolin by means ofⅪ①、FT一瓜、TEM、SEM、BET、正P． 111e analytical results showed that ideal coating result Can be obtained under strictly-controlled reaction conditions．The more urea concentration or less A13+ concentration lead formation independent AI(OH)3，the more A13+concentration or less urea concentration Can’t lead integrated coating，and the reaction time should be limited to a certain amount time． ne results of Our experiments showed that the surface of kaolin Was coated a smooth amorphous AI(OHb film,the surface physical of the particles is similar to