镁合金熔炼用陶瓷材料的分析-材料学专业毕业论文.docxVIP

中文摘要镁合金具有密度低、比强度和比刚度高、导热性好、屏蔽电磁 中文摘要 镁合金具有密度低、比强度和比刚度高、导热性好、屏蔽电磁 波能力强，可回收利用等优点，然而镁合金的耐腐蚀性较差限制了 其广泛应用。采用陶瓷部件或采用陶瓷内衬应用于镁合金熔炼及成 型设备中，可以最大限度地避免镁合金生产过程中混入Fe、Cu、 Cr等有害元素，提高镁合金制品的耐腐蚀性，这对于促进我国镁 工业的发展具有十分重要的意义。 本文首先阐明了本课题的背景及意义，然后分析了镁合金熔炼 的特点、镁合金熔炼用材料的要求，指出了氧化镁陶瓷是镁合金熔 炼用的理想材料。介绍了氧化镁的烧结特性、制各工艺及应用。以 轻质氧化镁为主要原料，通过添加一定量的氧化铝、纳米氧化锆及 少量的烧结助剂，在较低温度(1 550℃)下以固相烧结的方法制备 了MgO—A1203一Zr02(MAZ)复相陶瓷材料，研究了A1203、Zr02 对氧化镁陶瓷的烧结性能、机械性能的影响，并对MAZ陶瓷的组 成、显微结构、力学性能、抗热震性、抗侵蚀性、化学稳定性进行 了深入的分析。同时，对MAZ陶瓷最佳的制备工艺进行了探索， 测定了材料的各项性能指标，为其工业应用提供了必要的参数和依 据。 研究结果表明， A1203、Zr02极大地改善了氧化镁陶瓷的烧 结性能，MAZ陶瓷具有完善的显微结构，材料具有较高的力学性 能，优良的抗热震性与化学稳定性。在1 550℃烧结所制备的MAZ 陶瓷材料相对密度90％，抗弯强度o≥200MPa，断裂韧性 Kl C≥3MPa．m”2，热循环1 OO次后(△T=700℃)，剩余强度 O，≥140MPa，润湿角0=116 o，完全能够满足镁合金熔炼用材料 的要求。 关键词：镁合金氧化镁复相陶瓷力学性能热震性化学稳定性 ABSTRACTMagnesium ABSTRACT Magnesium alloys have many excellent properties such as specific strength，specific stiffness，thermal conductivity，shielding electromagnetic wave，recoverability and SO on，but they have not be applied widely due to their poor corrosion resistance．In order to prevent iron，copper and chromium and other harmful elements from going into alloys to the greatest extent during melting process， ceramics inner liner and ceramic parts carl be used for melting and casting equipment which can boost our country magnesium industry development greatly． The background and meaning of the study on ceramic materials applied for magnesium alloys melting were clarified in this paper firstly．Then the properties of magnesium alloys melting and demands for employed material and destruction mechanism were anal yzed． Magnesium oxide ceramics were considered as desired materials for melting magnesium alloy．Sinterability，fabrication and application of magnesium oxide ceramics were introduced．MgO—A1203一Zr02 system composite ceramic had been prepared successfully at 1 550℃ by solid state sintering with light·weight magnesium oxide as main raw material and certain content A1203，nanometer Zr02 as additives and a little sintering aid．Effects