镁合金微弧氧化陶瓷层表面有机导电涂层的制备及性能研究-材料科学与工程专业毕业论文.docxVIP

Abstra Abstract 西安理 西安理工大学硕士学位论文 Title: PREPARATION AND PROPERTIES OF ORGANIC CONDUCTIVE COATINGS ON MAGNESIUM ALLOYS WITH A MICRO-ARC OXIDATION CERAMIC LAYER Signature: Signature:Major: MATERIAL SCIENCE Signature: Signature: Name: Hairong SUN Supervisor: Associate prof. Junming LI Abstract Micro-arc oxidation (MAO) ceramic layers can significantly improve the corrosion and wear resistance of magnesium alloy substrate, achieving effective protection of the alloy components. But the oxide-based ceramic layer remarkably reduces the surface conductivity of metal substrates, so that the effect of the accumulated static electricity on the components for special service cannot be eliminated. Organic conductive coating that uses organic as substrate, and conductive filler as reinforced material, combines high corrosion resistance with excellent electrical conductivity. Therefore, integrating both not only can preserve the surface conductivity for microarc oxidized substrates, but also can close the porosity of MAO coatings, thus enhancing corrosion resistance. In this work, graphite particles with good electric conductivity was used as conductive filler, while epoxy was used as adhesives. Then, the conductive coating was fabricated by blending method as well as liquid coating, respectively. Additionaly, the effect of graphite particles content, size, adhesivediluent ratio and additive content on the conductive properties of organic coatings. The microstructure of conductive coating was observed by SEM, to analyze the filler distribution in adhesive, and furthermore, the conductivity mechanism was discussed. Finally, The corrosion resistance of conductive coating was studied by electrochemical test, immersion experiment and the binding force was characterized by grid method. The results show that the conductive coating of with minimum electric resistivity was prepared by blending method when the content of the graphite particles was 69.2 vol.%, particle size was 5 μm and ad